A) according to this reaction:
by using ICE table:
NH2OH(aq) + H2O(l) → HONH3+(aq) + OH-
initial 0.4 M 0 0
change -X +X +X
Equ (0.4-X) X X
when Kb = [OH-][HONH3+]/[NH2OH]
when we have Kb = 1.1x10^-8 so,
by substitution:
1.1x10^-8 = X^2/(0.4-X) by solving this equation for X
∴X = 6.6x10^-5 M
∴[OH] = 6.6x10^-5 M
when POH = - ㏒[OH]
∴POH = -㏒(6.6x10^-5)= 4.18
∴PH = 14 - POH = 14 - 4.18
= 9.82
when PH = -㏒[H+]
∴[H+] = 10^9.82 = 1.5x10^-10 M+0.02molHcl
= 0.02
∴ the new value of PH = -㏒(0.02)
∴PH = 1.7
B) according to this reaction:
by using ICE table:
HONH3+(aq) → H+(aq) + HONH2(aq)
intial 0.4 0 0
change -X +X +X
Equ (0.4-X) X X
when Ka HONH3Cl = 9.09x10^-7
and Ka = [H+][HONH2] / [HONH3+]
So by substitution and we can assume [HONH3+] = 0.4 as the value of Ka is so small so,
9.09x10^-7 = X^2 / 0.4 by solving for X
∴ X = 6 x 10 ^-4
∴[H+] = 6x10^-4
PH = -㏒[H+]
= -㏒ (6x10^-4) = 3.22
when [H+] = 6x10^-4 + 0.02 m HCl
∴new value of PH = -㏒(6x10^-4+0.02)
= 1.69
C) when we have pure H2O and PH of water = 7
So we can get [H+] when PH = -㏒[H+]
∴[H+] = 10^-7 + 0.02MHCl
= 0.02
∴new value of PH = -㏒0.02
PH = 1.7
d) when HONH2 & HONH3Cl have the same concentration and Hcl added to them so we can assume that PH=Pka
and when we have Ka for HONH3Cl = 9.09x10^-7
So we can get the Pka:
Pka = -㏒Ka
= -㏒9.09x10^-7
= 6.04
∴PH = 6.04
and because of the concentration of the buffer components, HONH2 & HONH3Cl have 0.4 M and the adding of HCl = 0.02 M So PH will remain very near to 6
Answer:
a new discover a new theory
Answer:
acid rain is a type of mixture that has a chemical substance that harms people, and can lead to possibly death.
Explanation:
Answer:
The sound waves travel from the outer ear and in through the auditory canal, causing the eardrum, or tympanic membrane, to vibrate. This, in turn, causes the three small bones, known as the ossicles, or the hammer, the anvil and the stirrup, in the middle ear to move.
Answer:
jet streams
Explanation:
THE JET STREAM Narrow bands of exceedingly high speed winds are known to exist in the higher levels of the atmosphere at altitudes ranging from 20,000 to 40,000 feet or more. They are known as jet streams.
