Answer:
One: <u>Selenium</u> is Paramagnetic
Explanation:
Those compounds which have unpaired electrons are attracted towards magnet. This property is called as paramagnetism. Lets see why remaining are not paramagnetic.
Electronic configuration of Scandium;
Sc = 21 = 1s², 2s², 2p⁶, 3s², 3p⁶, 4s², 3d¹
Sc³⁺ = 1s², 2s², 2p⁶, 3s², 3p⁶
Hence in Sc³⁺ there is no unpaired electron.
Electronic configuration of Bromine;
Br = 35 = 1s², 2s², 2p⁶, 3s², 3p⁶, 4s², 3d¹⁰, 4p⁵
Br⁻ = 1s², 2s², 2p⁶, 3s², 3p⁶, 4s², 3d¹⁰, 4p⁶
Hence in Br⁻ there is no unpaired electron.
Electronic configuration of Magnesium;
Mg = 12 = 1s², 2s², 2p⁶, 3s²
Mg²⁺ = 1s², 2s², 2p⁶
Hence in Mg²⁺ there is no unpaired electron.
Electronic configuration of selenium;
Se = 34 = 1s², 2s², 2p⁶, 3s², 3p⁶, 4s², 3d¹⁰, 4p⁴
Or,
Se = 34 = 1s², 2s², 2p⁶, 3s², 3p⁶, 4s², 3d¹⁰, 4px², 4py¹, 4pz¹
Hence in Se there are two unpaired electrons hence it is paramagnetic in nature.
(a) Iron (iii) sulphate:
From the periodic table:
mass of iron = 55.845 grams
mass of sulphur = 32.065 grams
mass of oxygen = 16 grams
Iron (iii) sulphate has the formula: Fe2(SO4)3
molar mass = 2(55.845) + 3(32.065) + 3(4)(16) = 399.885 grams
(b) Sodium hydroxide:
From the periodic table:
mass of sodium = 22.989 grams
mass of oxygen = 16 grams
mass of hydrogen = 1 gram
Sodium hydroxide has the formula: NaOH
molar mass = 22.989 + 16 + 1 = 39.989 grams
(c) Barium carbonate
From the periodic table:
mass of barium = 137.327 grams
mass of carbon = 12 grams
mass of oxygen = 16 grams
Barium carbonate has the formula: BaCO3
molar mass = 137.327 + 12 + 3(16) = 197.327 grams
(d) ammonium nitrate:
From the periodic table:
mass of nitrogen = 14 grams
mass of hydrogen = 1 gram
mass of oxygen = 16 grams
Ammonium nitrate has the formula: NH4NO3
molar mass = 14 + 4(1) + 14 + 3(16) = 80 grams
(e) Lead (iv) oxide
From the periodic table:
mass of lead = 207.2 grams
mass of oxygen = 16 grams
Lead (iv) oxide has the formula: PbO2
molar mass = 207.2 + 2(16) = 239.2 grams
From the above calculations, we can see that:
Iron (iii) sulphate has the greatest mass.
