Following reaction is involved in above system
HOCl(aq) ↔ H+(aq) + OCl-<span>(aq)
</span>OCl-(aq) + H2O(l) ↔ HOCl(aq) + OH-<span>(aq)
</span>
Now, if the system is obeys 1st order kinetics we have
K = [OCl-][H+<span>]/[HOCl] ............. (1)
</span>∴ [HOCl-] / [OCl-] = [H+] (1 / 3.0 * 10-8<span>) ............. (2)
</span>
and now considering that system is obeying 2nd order kinetics, we have
K = [OH-][HOCl-] / [OCl-] ................. (3<span>)
</span>Subs 2 in 3 we get
K = [OH-][H+] (1 / 3.0 * 10-8<span>)
</span>we know that, [OH-][H+] = 10<span>-14
</span>∴K = 3.3 * 10<span>-7
</span>
Thus, correct answer is e i.e none of these
Answer:
Explanation:
first write the equilibrium equaion ,
⇄
assuming degree of dissociation =1/10;
and initial concentraion of =c;
At equlibrium ;
concentration of
is very small so can be neglected
and equation is;
=
composiion ;
In a balloon there is a low pressure within the balloon. This means that the particles are more spaced out. Wheras in the cylinder they are under high pressure, meaning that the particles are much closer together!