<span>The overall reaction is as follows:
H2O2 + 2ClO2 => 2ClO2- + O2 + 2H+
Half cell reactions:
</span><span>ClO2 + e- => ClO2-
</span><span>H2O2 => O2 + 2H+ + 2e- </span>
As a base is added to an acidic solution, the H+ ions in solution that make it acidic are slowly neutralized into water (via OH-, the base). As these ions are converted into water the concentration of them decreases, so the pH decreases, as they are directly related.
Hope this helps!
1 mol = 6.022 x 10²³ atoms
In order to find how many atoms, dimly multiply the amount of moles you have by 6.022 x 10²³ or Avogadro's number.
So you have 1.75 mol CHC1₃ x (6.022x10²³) = 1.05385 x 10²⁴ atoms of CHCl₃
But now you have to round because of the rules of significant figures so you get 1.05 x 10²⁴ atoms of CHCl₃
Answer:
Axial
Explanation:
In the most stable conformation of Cis-3-tert-Butylcyclohexanol, the tert-butyl group is at equatorial position and the alcohol group is in the axial position.
If the tert-butyl group is placed in equatorial position, repulsions are minimized. The bulkier the group, the greater the energy difference between the axial and equatorial conformers. Hence for a ring having a bulky substituent, such bulky substituent is better placed in the equatorial position.
The energy difference between the conformers of Cis-3-tert-Butylcyclohexanol is so high that the compound is almost "frozen" in a conformation where the tert-butyl groups are equatorial and the -OH groups are axial. This conformer is more stable by 24 KJ/mol.
