580 grams of boiling water (temperature 100°C, specific heat capacity 4.2 J/K/gram) are poured into an aluminum pan whose mass i
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Answer:
The product is cyclohexanol
Explanation:
Firstly,
A ketone undergo a borohydride reduction reaction to form an alcohol as below,
R-CO-R' ⇒ R-CO(OH)-R'
- IR Spectrum confirms that alcohol group is existed with the peak at 3400 cm⁻¹
- From 1H-NMR, the product has 10 hydrogen atoms, the MS suggest that the formula is C₅H₁₀O (M = 86). With this formula, the alcohol is monosaturated. Since, the substance already underwent reduction reaction, the only way to suggest a monosaturated compound is a cyclic alcohol. So the compound is cyclopentanol.
- Check with other spectroscopic properties,
- 3 signals of 13C NMR confirms the structure is symmetrical, δ 24.2, (-<u>C</u>H₂-CH₂-CH(CH₂-)-OH), δ 35.5 (-CH₂-<u>C</u>H₂-CH(CH₂-)-OH), δ 73.3 (-CH₂-CH₂-<u>C</u>H(CH₂-)-OH).
- 1H NMR confirms,
1.56 δ (4H, triplet) - (-C<u>H</u>₂-CH₂-CH-OH) ; triplet as coupling with 2 H,
1.78 δ (4H, multiplet) - (-CH₂-C<u>H</u>₂-CH-OH); multiplet as coupling with 2H of CH₂, 1 H of CH
3.24 δ (1H, quintet); - (-CH₂-CH₂-C<u>H</u>(CH₂-)-OH), coupling with4 H of 2 group of CH₂
3.58 δ (1H, singlet); - (-CH₂-CH₂-CH(CH₂-)-O<u>H</u>), hydrogen of alcohol group, not tend to coupling with other hydrogen
- Speed=25m/s
- Time=45min=(45×60)s=2700s
Answer: 4.5 moles of can be made from complete reaction of 3.0 moles of Al.
Explanation:
The given reaction equation is as follows.
This shows that 2 moles of Al reacts with 6 moles of HCl. So, the amount of HCl required to react with 1 mole Al is three times the amount of HCl.
Therefore, 3 moles of Al will react with 9 moles of HCl to give 3 moles of and
moles of
.
The reaction equation now will be as follows.
The moles can also be written as 4.5 moles.
Thus, we can conclude that 4.5 moles of can be made from complete reaction of 3.0 moles of Al.