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kkurt [141]
3 years ago
15

A bomb calorimeter has a heat capacity of 783 J/oC and contains 254 g of water whose specific heat capacity is 4.184 J/goC. How

much heat, in kilojoules, is evolved or absorbed by a reaction when the temperature goes from 23.73 oC to 26.01 oC? cH2O = 4.184 J/g.K
Chemistry
1 answer:
IrinaK [193]3 years ago
7 0

Answer : The amount of heat evolved by a reaction is, 4.81 kJ

Explanation :

Heat released by the reaction = Heat absorbed by the calorimeter + Heat absorbed by the water

q=[q_1+q_2]

q=[c_1\times \Delta T+m_2\times c_2\times \Delta T]

where,

q = heat released by the reaction

q_1 = heat absorbed by the calorimeter

q_2 = heat absorbed by the water

c_1 = specific heat of calorimeter = 783J/^oC

c_2 = specific heat of water = 4.184J/g^oC

m_2 = mass of water = 254 g

\Delta T = change in temperature = T_2-T_1=(23.73-26.01)=-2.28^oC

Now put all the given values in the above formula, we get:

q=[(783J/^oC\times -2.28^oC)+(254g\times 4.184J/g^oC\times -2.28^oC)]

q=-4208.28J=-4.81kJ

Therefore, the amount of heat evolved by a reaction is, 4.81 kJ

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Answer:

18.075 mL of NaOH solution was added to achieve neutralization

Explanation:

First, let's formulate the chemical reaction between nitric acid and sodium hydroxide:

NaOH + HNO3 → NaNO3 + H2O

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63.01 g of HNO3 ----- 1 mole

8.2 g of HNO3 ----- x = (8.2 g × 1 mole)/63.01 g = 0.13014 moles of HNO3

So far we added 8.2 grams of nitric acid (0.13014 moles) in 1 L of water.

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So, we now know that in the 25 mL aliquot to be titrated we have 0.0032535 moles of HNO3. As we stated before, 1 mole of NaOH will react with 1 mole of HNO3, hence 0.0032535 moles of HNO3 have to react with 0.0032535 moles of NaOH to achieve neutralization. Let's calculate then, in which volume of the given NaOH solution we have 0.0032535 moles:

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\large \boxed{\text{5.9 s}}

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