Answer:
Explanation:
The correct statement is:
When 1 mol each of C₂H₅OH and CH₃CO₂H are allowed to react in 1 L of the solvent dioxane, equilibrium is established when 1/3 mol of each of the reactants remains. Calculate the equilibrium constant for the reaction. (Note: Water is a solute in this reaction.)
<u>1. Equilibrium equation</u>
- C₂H₅OH + CH₃CO₂H ⇄ CH₃CO₂C₂H₅ + H₂O
↑ ↑ ↑ ↑
ethanol acetic acid ethyl acetate water
<u>2. Equilibrium constant</u>
- Keq = [Products] / [Reactants], each raised to tis stoichiometrical coefficient.
Since water is also a solute in this reaction (the solvent is dioxane) its concentration will appear in the equilibrium constant.
<u>3. Equlibrium concentrations:</u>
Moles
C₂H₅OH + CH₃CO₂H ⇄ CH₃CO₂C₂H₅ + H₂O
Initial 1 1 0 0
Change -2/3 -2/3 +2/3 +2/3
End 1/3 1/3 2/3 2/3
Since the volume is 1 liter, the concentration is equal to the number of moles
<u>4. Calculations:</u>
![Keq=\frac{[CH_3CO_2C_2H_5]\cdot [H_2O]}{[C_2H_5OH]\cdot [CH_3CO_2H]}=\frac{2/3\cdot 2/3}{1/3\cdot 1/3}=4](https://tex.z-dn.net/?f=Keq%3D%5Cfrac%7B%5BCH_3CO_2C_2H_5%5D%5Ccdot%20%5BH_2O%5D%7D%7B%5BC_2H_5OH%5D%5Ccdot%20%5BCH_3CO_2H%5D%7D%3D%5Cfrac%7B2%2F3%5Ccdot%202%2F3%7D%7B1%2F3%5Ccdot%201%2F3%7D%3D4)
Dropping a water balloon on the ground
When a base, an acid, or a salt is dissolved in water it conducts electric currents
Ex. NaCl (salt)
<u>Answer:</u> The mass of solid is 81.24 grams
<u>Explanation:</u>
We are given:
Volume of solid and liquid together = 87.0 mL
To calculate density of a substance, we use the equation:
......(1)
Density of liquid solvent = 0.865 g/mL
Mass of liquid solvent = 49.7 g
Putting values in equation 1, we get:

Density of solid = 2.75 g/mL
Volume of solid = [87.0 - 57.46] mL = 29.54 mL
Putting values in equation 1, we get:

Hence, the mass of solid is 81.24 grams