Here we have to draw the four isomers of the compound 3-bromo-4-fluorohexane.
The four isomers of the compound is shown in the figure.
In an organic molecule the chiral -C center is that where four (4) different groups are present. In 3-bromo-4-fluorohexane the 3 and 4 positions are chiral centers. The possible isomers of a molecule can be obtained from the formula 2n. As here 2 chiral centers are present thus number of stereoisomers will be 2×2 = 4.
The four different isomers as shown in the figure are 3R-, 4R-; 3S-, 4S; 3R, 4S and 3S-, 4R- 3-bromo-4-fluorohexane.
In the 3-bromo-4-fluorohexane the functional groups are -Br, C₂H₅, -C₃H₆F and -H for 3-position and -F, -C₂H₅, -C₃H₆ and -H for 4-position respectively.
The priority of the -3 position will be Br > C₃H₆F > C₂H₅ > H and for -4 position F > C₃H₆Br > C₂H₅ > H. If the rotation from the higher priority group to lower is clockwise and anticlockwise then the S- and R- notation are used respectively. However if the -H atom is present at the horizontal position then the notation will be reverse.
Thus the four isomers of the compound is shown.
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Answer:
0.74 grams of methane
Explanation:
The balanced equation of the combustion reaction of methane with oxygen is:
it is clear that 1 mol of CH₄ reacts with 2 mol of O₂.
firstly, we need to calculate the number of moles of both
for CH₄:
number of moles = mass / molar mass = (3.00 g) / (16.00 g/mol) = 0.1875 mol.
for O₂:
number of moles = mass / molar mass = (9.00 g) / (32.00 g/mol) = 0.2812 mol.
- it is clear that O₂ is the limiting reactant and methane will leftover.
using cross multiplication
1 mol of CH₄ needs → 2 mol of O₂
??? mol of CH₄ needs → 0.2812 mol of O₂
∴ the number of mol of CH₄ needed = (0.2812 * 1) / 2 = 0.1406 mol
so 0.14 mol will react and the remaining CH₄
mol of CH₄ left over = 0.1875 -0.1406 = 0.0469 mol
now we convert moles into grams
mass of CH₄ left over = no. of mol of CH₄ left over * molar mass
= 0.0469 mol * 16 g/mol = 0.7504 g
So, the right choice is 0.74 grams of methane
System A undergoes an increase in entropy while system B undergoes a decrease in entropy.
Entropy is the degree of disorderliness of a system. The entropy of a system depends on the number of particles present in the system as well as the state of matter.
Entropy is increased when solid particles dissolve in water because more particles are produced thereby increasing the level of disorderliness in the system.
On the other hand, when vapor is condensed, the degree of disorderliness decreases as gases are converted to liquids.
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