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allsm [11]
3 years ago
9

A) Write a balanced equation. Be sure to include the state of the reactant and product in the equation.

Chemistry
1 answer:
liubo4ka [24]3 years ago
7 0
A)  5Ca(OH)₂ + 3H₃PO₄ → Ca₅(PO₄)₃(OH) + 9H₂O

B) m=158 g; w=0.830; m{Ca(OH)₂}=123 g

n(H₃PO₄) = m(H₃PO₄)/M(H₃PO₄) = mw/M(H₃PO₄) 
n(H₃PO₄) = 158g*0.830/(98.0g/mol) =  1.3382 mol

n{Ca(OH)₂}=m{Ca(OH)₂}/M{Ca(OH)₂}
n{Ca(OH)₂}=123g/(74.01g/mol)=1.6619 mol

Ca(OH)₂:H₃PO₄ = 5:3
1.6619:1.3382 = 5:4  the limiting reagent is a calcium hydroxide

m{Ca₅(PO₄)₃(OH)} = M{Ca₅(PO₄)₃(OH)}n{Ca(OH)₂}/5

m{Ca₅(PO₄)₃(OH)} = 502.3g/mol*1.6619/5=166.954 g*

*The statement of the problem is incorrect, surplus of a phosphoric acid reacts with a hydroxyapatite. The calculated quantity of a hydroxyapatite is not formed.
3Ca₅(PO₄)₃OH + H₃PO₄ = 5Ca₃(PO₄)₂ + 3H₂O


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Explanation :

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CH_3OH(g)+CO(g)\rightarrow HCH_3CO_2(g)

Now we have to calculate value of (\Delta G^o).

\Delta G^o=G_f_{product}-G_f_{reactant}

\Delta G^o=[n_{HCH_3CO_2(g)}\times \Delta G^0_{(HCH_3CO_2(g))}]-[n_{CH_3OH(g)}\times \Delta G^0_{(CH_3OH(g))}+n_{CO(g)}\times \Delta G^0_{(CO(g))}]

where,

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Now put all the given values in this expression, we get:

\Delta G^o=[1mole\times (-389.8kJ/mol)]-[1mole\times (-163.2kJ/mol)+1mole\times (-137.2kJ/mol)]

\Delta G^o=-89.4kJ/mol

The relation between the equilibrium constant and standard Gibbs, free energy is:

\Delta G^o=-RT\times \ln K

where,

\Delta G^o = standard Gibbs, free energy  = -89.4 kJ/mol = -89400 J/mol

R = gas constant  = 8.314 J/L.atm

T = temperature  = 30.0^oC=273+30.0=303K

K = equilibrium constant = ?

Now put all the given values in this expression, we get:

-89400J/mol=-(8.314J/L.atm)\times (303K)\times \ln K

K=2.6\times 10^{15}

Thus, the value of K for this reaction is, 2.6\times 10^{15}

4 0
4 years ago
what is the kinetic energy of the emitted electrons when cesium is exposed to uv rays of frequency 1.4×1015hz?
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