The frequency will not change
The initial kinetic energy of the boat and its rider is

After Sam stops it, the final kinetic energy of the boat+rider is

because its final velocity is zero.
For the law of conservation of energy, the work done by Sam is the variation of kinetic energy of the system:

where the negative sign is due to the fact that the force Sam is applying goes against the direction of motion of the boat.
Answer: 
Explanation:
The angular diameter
of a spherical object is given by the following formula:

Where:
is the actual diameter
is the distance to the spherical object
Hence:

This is the angular diameter
If each mL has 30 grams of the substance in it, then 60 mL have 1800 grams of mass in them. the weight of 1,800 grams of mass on Earth is (1.8 kg) x (9.8 m/s^2) = 17.6 newtons.