The effective nuclear charge is an innate property of a specific element. It is the pull of force that an electron feels from the nucleus. It is related to the valence electron by the equation: Z* = Z-S, where Z* is the effective nuclear charge, Z is the atomic number and S is the shielding constant.
For the following elements in the choices, these are their values of Z*:
Aluminum - +12.591
Beryllium - +1.912
Hydrogen - +1
Carbon - +4
The effective nuclear charge of Boron is +3. Thus, the answers are Aluminum and Carbon.
The element that will have the lowest electronegativity is an element with a small number of valence electrons and a large atomic radius.
Electronegativity of an element is the ability or power of that element in a molecule to attract electrons to its Valence electrons. The following are the properties of electronegativity:
- It increases across a period from left to right of the periodic table,
- It decreases down the periodic table groups
- Group 1 elements are the least (lowest) electronegative elements. These elements have the lowest valence electrons with a large atomic radius.
- Group 7 elements are the most electronegative elements.
Atomic radius of elements increase down a group because of a progressive increase in the number of shells occupied by electrons which increases the size. But it decreases across a period because electrons are accommodated within the same shell leading to greater attraction by the protons in the nucleus.
Learn more about electronegativity of elements here:
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"cg" is centigram, which is one-hundredth of a gram.
I will first convert from g to cg (multiply by 100), then from mL to L (multiply by 1000).
The molar mass of CuCl2 is 134.45 g/mol; therefore, you divide 2.5 g of CuCl2 by 134.45 g of CuCl2 leaving you with 0.019 moles
Answer:
b. The splitting of the d-orbitals is smaller in the [Ni(Cl)6]4- complex than in the [Ni(en)3]2+ complex.
Explanation:
The spectrochemical series is an arrangement of ligands in increasing order of their magnitude of crystal field splitting.
Ligands that occurs towards the right in the series are called strong field ligands and they tend to cause a greater magnitude of crystal field splitting. Ligands that occur towards the left hand side in the series are called weak field ligands and they tend to cause a lesser magnitude of crystal field splitting.
Since Cl^- is a weak field ligand, it causes a lesser magnitude of d orbital splitting compared to ethylenediammine (en) which causes a greater magnitude of d orbital splitting.
Hence; the splitting of the d-orbitals is smaller in the [Ni(Cl)6]4- complex than in the [Ni(en)3]2+ complex.