For which gases does the ratio of PV to RT equal a constant?
1 answer:
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Explanation:
Half life of zero order and second order depends on the initial concentration. But as the given reaction slows down as the reaction proceeds, therefore, it must be second order reaction. This is because rate of reaction does not depend upon the initial concentration of the reactant.
a. As it is a second order reaction, therefore, doubling reactant concentration, will increase the rate of reaction 4 times. Therefore, the statement a is wrong.
b. Expression for second order reaction is as follows:
the above equation can be written in the form of Y = mx + C
so, the plot between 1/[A] and t is linear. So the statement b is true.
c.
Expression for half life is as follows:
As half-life is inversely proportional to initial concentration, therefore, increase in concentration will decrease the half life. Therefore statement c is wrong.
d.
Plot between A and t is exponential, therefore there is no constant slope. Therefore, the statement d is wrong
Here we have to get the spin of the other electron present in a orbital which already have an electron which has clockwise spin.
The electron will have anti-clockwise notation.
We know from the Pauli exclusion principle, no two electrons in an atom can have all the four quantum numbers i.e. principal quantum number (n), azimuthal quantum number (l), magnetic quantum number (m) and spin quantum number (s) same. The importance of the principle also restrict the possible number of electrons may be present in a particular orbital.
Let assume for an 1s orbital the possible values of four quantum numbers are n = 1, l = 0, m = 0 and s = .
The exclusion principle at once tells us that there may be only two unique sets of these quantum numbers:
1, 0, 0, + and 1, 0, 0, -
.
Thus if one electron in an orbital has clockwise spin the other electron will must be have anti-clockwise spin.