Equilibrium expression is ![Keq = \frac{[H3O+][HCO3^-]}{[H2CO3]}\\](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%2B%5D%5BHCO3%5E-%5D%7D%7B%5BH2CO3%5D%7D%5C%5C)
<u>Explanation:</u>
Equilibrium expression is denoted by Keq.
Keq is the equilibrium constant that is defined as the ratio of concentration of products to the concentration of reactants each raised to the power its stoichiometric coefficients.
Example -
aA + bB = cC + dD
So, Keq = conc of product/ conc of reactant
![Keq = \frac{[C]^c [D]^d}{[A]^a [B]^b}](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BC%5D%5Ec%20%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%20%5BB%5D%5Eb%7D)
So from the equation, H₂CO₃+H₂O = H₃O+HCO₃⁻¹
![Keq = \frac{[H3O^+]^1 [HCO3^-]^1}{[H2CO3]^1 [H2O]^1}](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%5E%2B%5D%5E1%20%5BHCO3%5E-%5D%5E1%7D%7B%5BH2CO3%5D%5E1%20%5BH2O%5D%5E1%7D)
The concentration of pure solid and liquid is considered as 1. Therefore, concentration of H2O is 1.
Thus,
![Keq = \frac{[H3O+][HCO3^-]}{[H2CO3]}\\](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%2B%5D%5BHCO3%5E-%5D%7D%7B%5BH2CO3%5D%7D%5C%5C)
Therefore, Equilibrium expression is ![Keq = \frac{[H3O+][HCO3^-]}{[H2CO3]}\\](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%2B%5D%5BHCO3%5E-%5D%7D%7B%5BH2CO3%5D%7D%5C%5C)
Answer:
147.2g
Explanation:
The full solution can be found in the image attached. Graham's law was applied to the problem. The rate of diffusion of a gas is inversely proportional to its molar mass or vapour density. Molar mass= 2vapour density
Helium,it has an atomic mass of 4,which means total no. of protons and neutrons,so I think you meant 2 protons and an atomic mass of 4
Answer:
Rate = k . [B]² . [C]
Explanation:
The dependence of the reaction rate on the concentration of the reactants is given by the reaction order of each one, as shown in the rate equation.
![Rate=k.[A]^{x} .[B]^{y} .[C]^{z}](https://tex.z-dn.net/?f=Rate%3Dk.%5BA%5D%5E%7Bx%7D%20.%5BB%5D%5E%7By%7D%20.%5BC%5D%5E%7Bz%7D)
where,
k is the rate constant
x, y, z are the reaction orders.
- <em>The rate of reaction is not affected by changing the concentration of species A.</em> This means that the reaction order for A is x = 0 since when its concentration changes, the rate stays the same.
- <em>Leaving all other factors identical, doubling the concentration of species B increases the rate by a factor of 4.</em> This means that the reaction order for B is y = 2, so when the concentration is doubled, the new rate is 2² = 4 times the initial rate.
- The rate of the reaction is linearly dependent on the concentration of C. This means that the reaction order for C is z = 1, that is, a linear dependence.
All in all, the rate equation is:
Rate = k . [B]² . [C]
Answer:
dG will be the same -20 kcal/mol
Explanation:
The dG can be expressed in terms of the G(products) - G(reactants). If the amount of enzyme is doubled the Gibbs energy of the reactants and products will be the same, so the substraction dG has the same value