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Radda [10]
3 years ago
13

At a certain temperature, the equilibrium constant, K c , Kc, for this reaction is 53.3. H 2 ( g ) + I 2 ( g ) − ⇀ ↽ − 2 HI ( g

) K c = 53.3 H2(g)+I2(g)↽−−⇀2HI(g)Kc=53.3 At this temperature, 0.700 mol H 2 0.700 mol H2 and 0.700 mol I 2 0.700 mol I2 were placed in a 1.00 L container to react. What concentration of HI HI is present at equilibrium?
Chemistry
1 answer:
Yanka [14]3 years ago
4 0

Answer:

1.099 M is the concentration of HI is present at equilibrium.

Explanation:

Initial concentration of hydrogen gas = [H_2]=\frac{0.700 mol}{1.00 L}=0.700 M

Initial concentration of iodine gas = [I_2]=\frac{0.700 mol}{1.00 L}=0.700 M

H_2+I_2\rightleftharpoons 2HI

Initially

0.700 M     0.700 M         0

(0.700-x)M   (0.700-x)      2x

Expression of an equilibrium constant is given by :

K_c=\frac{[HI]^2}{[H_2][I_2]}

53.3=\frac{4x^2}{(0.700-x)(0.700-x)}

Solving for x:

x = 0.5495 M

Concentration of HI is present at equilibrium:

2\times 0.5495 M=1.099 M

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a) 7.0.

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The mass of the hydrated sample (NiSO₄.xH₂O) = 5.0 g,

The mass of the anhydrous salt (NiSO₄) = 2.755 g,

The mass of water = 5.0 g - 2.755 g = 2.245 g.

∴ no. of moles of water = mass/molar mass = (2.245 g)/(18.0 g/mol) = 0.1247 mol.

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∴ water of crystallization in the sample (x) = no. of moles of water/no. of moles of anhydrous salt (NiSO₄) = (0.1247 mol)/(0.0178 mol) = 7.0.

<u><em>b) What is the full chemical name for the hydrate?</em></u>

The name of the salt (NiSO₄.7H₂O) is Nickel sulfate hepta hydrate.

<u><em>c) What is the molar mass of the hydrate? </em></u>

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The molar mass = molar mass of NiSO₄ + 7(molar mass of H₂O) = (154.75 g/mol) + 7(18.0 g/mol) = 280.83 g/mol.

<em><u>d) What is the mass % of water in the hydrate?</u></em>

The mass % of water = (mass of water)/(mass of hydrated sample) x 100 = (2.245 g)/(5.0 g) x 100 = 44.9%.

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