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Anastaziya [24]
3 years ago
6

The conjugation of the trans/cis product is likely diminished due to steric interactions between the cis-phenyl and the nearby v

inyl hydrogen. This interaction likely causes the phenyl ring to twist out of the plane, and thus no longer to be fully conjugated with the adjacent double bond. The trans-trans isomer has no such steric interactions, and thus it is expected to be more fully conjugated. The two isomers are thus may have different light absorbing properties.
Considering all this, which product stereoisomer do you expect to have the highest lambda max value in the UV-V is spectrum- the trans/trans or the cis/trans? Briefly explain your answer.
Chemistry
1 answer:
max2010maxim [7]3 years ago
8 0

Answer:

The trans/trans stereoisomer.

Explanation:

So, we are going to have two stereoisomers or arrangements for this chemical compound, that is the Cis/trans, the trans/trans.

For a compound to be seen with UV, the main or primary condition is conjugation or how conjugated the chemical specie or compound is.

Thus, the more the conjugation, the more or the higher the wavelength or lands value.

=> The Trans/trans stereoisomer will have the highest lamda value or wavelength because the energy gap in its π - π* Transitioning deceases due to the STERIC interactions, and the more the decrease in the energy gap, the more or the higher the lamda value or wavelength.

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Answer:

longitudinal

Explanation:

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4 0
2 years ago
If 15.00 mL of 0.0100 M Ca(IO3)2 solution are mixed with 0.500 g KI, what is the theoretical yield (in grams) of I2?
n200080 [17]

The theoretical yield of I2 in the reaction would be 0.23 g

<h3>Theoretical yield</h3>

This refers to the stoichiometric yield of a reaction.

From the equation of the reaction:

Ca(IO3)2 + 10 KI + 12 HCl → 6 I2 + CaCl2 + 10 KCl + 6 H2O

The mole ratio of Ca(IO3)2 and I2 is 1: 6

Mole of 15.00 mL, 0.0100 M Ca(IO3)2 = 15/1000 x 0.0100

                                                              = 0.00015 mole

Equivalent mole of I2 = 0.00015 x 6

                                      = 0.009 mole

mass of 0.0009 I2 = 0.0009 x 253.809

                                = 0.23 g

More on stoichiometric calculations can be found here: brainly.com/question/6907332

8 0
3 years ago
Describe in your own words, in terms of particle movement and energy, what occurs when a liquid is cooled to its freezing point.
IRINA_888 [86]
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Why does the fact that Americans are using less fertilizer not indicate a decline in American farming?
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4 0
3 years ago
Read 2 more answers
In experiment 1, how many moles of benzoic acid are present? how many moles of sodium bicarbonate are contained in 1 ml of a 10%
nexus9112 [7]

First, let us calculate the moles of solute or sodium bicarbonate is in the 1 ml solution.

<span>moles  = 1 mL * (1 g / 9 mL) = 0.11 moles</span>

 

The molar mass of sodium bicarbonate is 84 g/mol, therefore the mass is:

mass = 0.11 moles * 84 g/mol

<span>mass = 9.33 g</span>

6 0
3 years ago
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