Explanation:
Higher the frequency smaller will be the wavelength. Higher frequency have shorter wavelength and lower frequency waves have larger wavelength. Also, Beats are formed by the superposition of two waves with slightly different frequencies but with similar amplitudes. In time, waves switch between constructive interference and disruptive interference, giving the resultant wave a time-varying amplitude.
Answer:
Change in entropy for the reaction is
ΔS° = -268.13 J/K.mol
Explanation:
To calculate the change in entropy for the balanced reaction, we require the natural entropy of all the reactants and products in the reaction.
3 NO₂(g) + H₂O(l) → 2 HNO₃(l) + NO(g)
From Literature.
S°(NO₂) = 240.06 J/K.mol
S°(H₂O) = 69.91 J/K.mol
S°(HNO₃) = 155.60 J/K.mol
S°(NO) = 210.76 J/K.mol
These are the entropies of the reactants and products under standard conditions of 298.15 K and 1 atm.
Note that
ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)
Σ nᵢS°(for products) = [2 × S°(HNO₃)] + [1 × S°(NO)]
= (2 × 155.60) + (1 × 210.76) = 521.96 J/K.mol
Σ nᵢS°(for reactants) = [3 × S°(NO₂)] + [1 × S°(H₂O)]
= (3 × 240.06) + (1 × 69.91) =790.09 J/K.mol
ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)
ΔS° = 521.96 - 790.09 = -268.13 J/K.mol
Hope this Helps!!
Answer:
Activation energy of phenylalanine-proline peptide is 66 kJ/mol.
Explanation:
According to Arrhenius equation-
, where k is rate constant, A is pre-exponential factor,
is activation energy, R is gas constant and T is temperature in kelvin scale.
As A is identical for both peptide therefore-
![\frac{k_{ala-pro}}{k_{phe-pro}}=e^\frac{[E_{a}^{phe-pro}-E_{a}^{ala-pro}]}{RT}](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7Bala-pro%7D%7D%7Bk_%7Bphe-pro%7D%7D%3De%5E%5Cfrac%7B%5BE_%7Ba%7D%5E%7Bphe-pro%7D-E_%7Ba%7D%5E%7Bala-pro%7D%5D%7D%7BRT%7D)
Here
, T = 298 K , R = 8.314 J/(mol.K) and 
So, ![\frac{0.05}{0.005}=e^{\frac{[E_{a}^{phe-pro}-(60000J/mol)]}{8.314J.mol^{-1}.K^{-1}\times 298K}}](https://tex.z-dn.net/?f=%5Cfrac%7B0.05%7D%7B0.005%7D%3De%5E%7B%5Cfrac%7B%5BE_%7Ba%7D%5E%7Bphe-pro%7D-%2860000J%2Fmol%29%5D%7D%7B8.314J.mol%5E%7B-1%7D.K%5E%7B-1%7D%5Ctimes%20298K%7D%7D)
(rounded off to two significant digit)
So, activation energy of phenylalanine-proline peptide is 66 kJ/mol
<u><em>Answer:</em></u>
<u><em>Explanation:</em></u>
Phosphate ion has covalent bond. As we known , covalent bond is formed by sharing of electrons between two atoms. As in this case, P form three single covalent bond with three oxygen atoms and one double covalent bond with one oxygen . The formal charges is -3.
While He is present in mono atomic form
NaI have ionic bond which is formed by donating electrons from one atom and other accept.
Ag is present independently with no other atom.