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const2013 [10]
3 years ago
6

Carbon tetrachloride, CCl4, was once used as a dry cleaning solvent, but is no longer used because it is carcinogenic. At 55.8°C

, the vapor pressure of CCl4 is 52.7 kPa, and its enthalpy of vaporization is 29.82 kJ/mol. Use this information to estimate the normal boiling point (in °C) for CCl4.
Chemistry
1 answer:
joja [24]3 years ago
4 0
Use the Clausius-Clapeyron equation... 

<span>Let T1 be the normal boiling point, which will occur at standard pressure (P1), which is 101.3 kPa (aka 760 torr or 1.00 atm). You know the vapour pressure (P2) at a different temperature (T2). And you are given the enthalpy of vaporization. Therefore, we can use the Clausius-Clapeyron equation.

</span>ln(P_1/P_2) = \frac{-\delta H_{vap}}{R}  \times [\frac{1}{T_1} - \frac{1}{T_2}]<span>

</span><span>ln(101.3 kPa / 52.7 kPa) = (-29.82 kJ/mol / 8.314x10^{-3} kJ/molK) (1/T - 1/329 K) 
</span>
------ some algebra goes here ----- 

<span>T = 349.99K ...... or ...... 76.8C </span>

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1.15 atm

Explanation:

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Abuse of time and temperature has to do with a situation in which time is used in an improper way or food is not held at the correct temperature ultimately leading to food poisoning.

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