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KATRIN_1 [288]
3 years ago
14

A hypothetical covalent molecule, x–y, has a dipole moment of 1.44 d and a bond length of 163 pm. calculate the partial charge o

n a pole of this molecule in terms of e (where e is the charge on an electron).
Chemistry
1 answer:
Aneli [31]3 years ago
4 0
As we know,
                                     1 D  =  3.34 × 10⁻³⁰ C.m
So,
                                     1.44 D  =  ?
Solving for 1.44 D,
                                     =  (3.34 × 10⁻³⁰ C.m × 1.44 D) ÷ 1 D
                    
                         1.44 D  =  4.80 × 10⁻³⁰ C.m

Dipole Moment 
is given as,
 
                         Dipole Moment  =  q  ×  r    
Solving for q,
                         q  =  Dipole Moment / r    ------ (1)
Where,
                         Dipole Moment  =  4.80 × 10⁻³⁰ C.m

                         r  =  163 pm  =  1.63 × 10⁻¹⁰ m

Putting values in eq. 1,

                            q  =  4.80 × 10⁻³⁰ C.m / 1.63 × 10⁻¹⁰ m

                            q  =  2.94 × 10⁻²⁰ C

As,
                            1.602 × 10⁻¹⁹ C  =  1 e⁻
So,
                             2.94 × 10⁻²⁰ C  =  X e⁻

Solving for X,

                            X  =  (2.94 × 10⁻²⁰ C × 1 e⁻) ÷ 1.602 × 10⁻¹⁹ C

                                = 0.183 e⁻

Result:
           
So one element is containing + 0.183 e⁻ while the other element is containing - 0.183 e⁻.
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The reaction;
O(g) +O2(g)→O3(g), ΔH = sum of bond enthalpy of reactants-sum of food enthalpy of products.
ΔH = ( bond enthalpy of O(g)+bond enthalpy of O2 (g) - bond enthalpy of O3(g)
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