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Gnesinka [82]
3 years ago
12

What is the capillary rise of ethanol in a glass tube with a 0.1 mm radius if the surface tension of ethanol is 0.032Jm2 and the

density of ethanol is 0.71gcm3? Assume that the contact angle of ethanol in a glass tube is 0 degrees.
Chemistry
1 answer:
sweet [91]3 years ago
5 0

Answer: The capillary rise(h) in the glass tube is = 0.009m

Explanation:

Using the equation

h = 2Tcosθ/rpg

Given

Contact angle, θ = Zero

h = height of the glass tube=?

T = surface tension = 0.032J/m^2

r = radius of the tube = 0.1mm =0.0001m

p= density of ethanol = 0.71g/cm^3

g= 9.8m/s^2

h = (2 * 0.032 * cos 0)/( 710*9.8*0.0001)

h= 0.09m

Therefore the capillary rise in the tube is 0.09m

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Given a sample of poly[ethylene-stat-(vinyl acetate)] A.Calculate the mean repeat unit molar mass for a sample of poly[ethylene-
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a) The mean repeat unit molar mass for PEVA is 30.72 g/mol

b) degree of polymerization of the copolymer is 1300

Explanation:

Given that;

the wt% of copolymer consist of 12.9 wt% of vinyl acetate and 87.1 wt% Ethylene.

Basis: 100 g of PEVA consist of 12.9 of vinyl acetate and 87.1g of Ethylene.

now we calculate the mole fraction of vinyl acetate Ethylene in the copolymer;

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so

moles of vinyl acetate = wt. of vinyl acetate / molecular weights of vinyl acetate

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moles of Ethylene = wt. of Ethylene / molecular weights of Ethylene

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Total moles = 0.1498 mol + 3.1052 mol = 3.255 mol

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mole percent of vinyl acetate X_{V} = moles of vinyl acetate / total  moles

X_{V} = (0.1498 mol / 3.255 mol) × 100

X_{V}  = 4.6%

mole percent of Ethylene X_{E} = moles of Ethylene / total  moles

X_{E}  = (3.1052 mol / 3.255 mol) × 100

X_{E}  = 95.397% ≈ 95.4%

we know that, mean repeat unit molar mass for a sample = ∑X_{i}M_{i}

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so or the PEVA

mean repeat unit molar mass M = ( X_{V}M_{V}) + ( X_{E}M_{E})

so we substitute

M = ( 4.6% × 86.09) + ( 95.4% × 28.05 )

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Therefore, The mean repeat unit molar mass for PEVA is 30.72 g/mol

b)

Degree of polymerization

DP_{n} = \frac{M_{n} }{M}

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so we substitute

DP_{n} = 39,870 g/mol / 30.72 g/mol

DP_{n}  = 1297.85 ≈ 1300   { 3 significance figure }

Therefore, degree of polymerization of the copolymer is 1300

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