Answer:
14. B 15. D 16. C 17. B
Explanation:
The spontaneous reaction that occurs when the cell operates is shown below:
⇒
We need to select the correct option from the list below for the following questions.
(A) Voltage increases. (B) Voltage decreases but remains > zero. (C) Voltage becomes zero and remains at zero. (D) No change in voltage occurs. (E) Direction of voltage change cannot be predicted without additional information.
14. A 50-milliliter sample of a 2-molar 
solution is added to the left beaker.
If a 50-milliliter sample of a 2-molar solution is added to the left beaker, the voltage decreases but its value remains greater than zero. The correct option is B
15. The silver electrode is made larger.
If the silver electrode is made larger, no change in the value of the voltage since we don't have the idea of the initial value. The correct option is D.
16. The salt bridge is replaced by a platinum wire.
If the salt bridge is replaced by a platinum wire, there will be no passage of electrons because electrons can't pass through a platinum wire. Therefore, the voltage will be zero and remains at zero. The correct option is C.
17. Current is allowed to flow for 5 minutes.
If current is allowed to flow for 5 minutes, the voltage decreases but its value remains greater than zero. The correct option is B.
Answer: No, a<span>t high pressures, volume of a real gas does not compare with the volume of an ideal gas under the same conditions.
Reason:
For an ideal gas, there should not be any intermolecular forces of interaction. However, for real gases there are intermolecular forces of interaction like dipole-dipole and dipole-induced dipole. Further, at high pressures, molecules are close by. Hence, extend of these intermolecular forces is expected to be high. This results in decreases in volume of real gas. Thus, </span>volume of a real gas does not compare with the volume of an ideal gas under the same conditions.
Intermolecular forces are forces of interaction that are operative between two different molecules. They are of follow types
1) Dipole- dipole interaction
2) Hydrogen bonds
3) vander Waal's forces
Depending upon the polarity and constitution molecule above forces are operable.
for instance, in case of ammonia, Hydrogen bonds exist because hydrogen atom is attached to electronegative element i.e. N
HCl and CO are polar molecules, so dipole-dipole interaction is operative in these molecules.
Finally in case of CO2, vander Waal's forces of interaction is operable because it is a non-polar molecule.
PbCr04 + P4O10
Hope this helps!
