Answer:
A- upfield
B- down field
C- splitting
D- chemical shift
E- integration
Explanation:
NMR is a spectroscopic technique commonly used to observe the magnetic fields around the nucleus of atoms in a compound under investigation.
A chemical shift is the difference in parts per million (ppm) between the resonance frequency of the observed protons in the compound under study and that of the tetramethylsilane (TMS) (the reference compound in NMR with a chemical shift of zero ppm because all protons in the compound are equivalent).
If signals appear close to the reference signal, the signals are said to appear upfield. If the signals appear far away from the reference, they are said to appear down field.
The presence of protons cause splitting of peaks to the magnitude of n+1. n is the number of neighboring protons. Splitting refers to the appearance of multiple peaks for a single nucleus due to neighboring nuclei.
The area of a signal that corresponds to the number of nuclei at that frequency is called the integration.
It is 50. The answer is 50. 10x5=50 50x1=50
The heat that creates this temperature change coming from change in the internal energy of the system as per as first law of thermodynamics.
<h3>What is Boyle's law ?</h3>
A law stating that the pressure of a given mass of an ideal gas is inversely proportional to its volume at a constant temperature.
As we know, Boyle's law only works when the gas is kept at a constant temperature
Here,
When volume of gases decreased, it means work done has occurred on the system, so the work done is used for raising internal energy of the gas and the other is released as the thermal energy.
So,
According to 1st law of thermodynamics,
we know Q = ΔU + W i.e, change in internal energy and work done. So this is a reason. Changing temperature occurs.
Learn more about Internal enrgy here ;
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Identical electron configurations : K⁺ and Cl⁻
<h3>Further explanation </h3>
In an atom, there are levels of energy in the shell and sub-shell
This energy level is expressed in the form of electron configurations.
Charging electrons in the sub-shell uses the following sequence:
<em>1s², 2s², 2p⁶, 3s², 3p⁶, 4s², 3d¹⁰, 4p⁶, 5s², 4d¹⁰, 5p⁶, 6s², etc. </em>
S²⁻ : [Ne] 3s²3p⁶
Cl : [Ne] 3s²3p⁵
K⁺ : 1s² 2s² 2p⁶ 3s² 3p⁶
Cl⁻ : 1s² 2s² 2p⁶ 3s²3p⁶
S :[Ne] 3s²3p⁴
Ar : [Ne] 3s²3p⁶
Cl⁻ : 1s² 2s² 2p⁶ 3s²3p⁶
K : 1s² 2s² 2p⁶ 3s² 3p⁶4s¹