A gas is heated from 263.0 K to 298.0 K and the volume is increased from 24.0 liters to 35.0 liters by moving a large piston wit
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Answer:
The new equilibrium total pressure will be increased to one-half to initial total pressure.
Explanation:
From the information given :
The equation of the reaction can be represented as;
From above equation:
2 moles of sulphur dioxide reacts with 1 mole of oxygen (i.e 2 moles +1 mole =3 moles ) to give 2 moles of sulphur trioxide
So; suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished.
So if this process takes place ; the equilibrium will definitely shift to the side with fewer moles , thus the equilibrium will shift to the right. As such; there is increase in pressure.
Let the total pressure at the initial equilibrium be
and the total pressure at the final equilibrium be
According to Boyle's Law; Boyle's Law states that the pressure of a fixed mass of gas is inversely proportional to the volume, provided the temperature remains constant.
Thus;
P ∝ 1/V
P = K/V
PV = K
where K = constant
So;
PV = constant
Hence;
From the foregoing; since the volume is decreased to one- half to initial Volume; then ,
also;
Thus ;
Dividing both sides by
From ;
Thus; The new equilibrium total pressure will be increased to one-half to initial total pressure.
Answer:
66.67%
Explanation:
From the given information:
mass of cyclohexane = 2.9949 grams
density of cyclohexane = 0.779 g/mL
Recall that:
Density = mass/volume
∴
Volume = mass/density
So, the volume of cyclohexane = 2.9949 g/ 0.779 g/mL
= 3.8445 mL
Also,
mass of propylbenzene = 1.6575 grams
density of propylbenzene = 0.862 g/mL
Volume of propylbenzene = 1.6575 g/ 0.862 g/mL
= 1.9229 mL
The volume % composition of cyclohexane from the mixture is:
= 66.67%