The pressure inside a sealed container is 97.9 kPa when the temperature is 298 K.
1 answer:
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Answer:
Here's what I get
Explanation:
(a) Intermediates
The three structures below represent one contributor to the resonance-stabilized intermediate, in which the lone pair electrons on the heteroatom are participating (the + charge on the heteroatoms do not show up very well).
(b) Relative Stabilities
The relative stabilities decrease in the order shown.
N is more basic than O, so NH₂ is the best electron donating group (EDG) and will best stabilize the positive charge in the ring. However, the lone pair electrons on the N in acetanilide are also involved in resonance with the carbonyl group, so they are not as available for stabilization of the ring.
(c) Relative reactivities
The relative reactivities would be
C₆H₅-NH₂ > C₆H₅-OCH₃ > C₆H₅-NHCOCH₃
Answer:
The volume of NO₂ gas collected over water at 25.0 °C is 1.68 Liters.
Explanation:
Moles of copper =
According to reaction, 1 mol of copper gives 2 moles of nitrogen dioxide gas.
Then 0.03613 moles of copper will give:
of nitrogen dioxide gas
Moles of nitrogen dioxide gas = n = 0.06326 mol
Pressure of the gas = P
P = Total pressure - vapor pressure of water
P = 726 mmHg - 23.8 mmHg = 702.2 mmHg
P = 0.924 atm (1 atm = 760 mmHg)
Temperature of the gas = T = 25.0°C =298.15 K
Volume of the gas = V
V = 1.68 L
The volume of NO₂ gas collected over water at 25.0 °C is 1.68 Liters.