Answer : The value of 
for this reaction is 36.18 kJ
Explanation :
First law of thermodynamic : It states that the energy can not be created or destroyed, it can only change or transfer from one state to another state.
As per first law of thermodynamic,
where,
= internal energy of the system
q = heat added or rejected by the system
w = work done
As we are given that:
q = 38.65 kJ
w = -2.47 kJ (system work done on surrounding)
Now put all the given values in the above expression, we get:
Therefore, the value of for this reaction is 36.18 kJ
Answer:
secrete cytotoxic substance which triggers apoptosis of target cell.
Explanation:
Cytotoxic T cells have cell surface receptor which recognizes the antigen present on the receptor of target cell. This interaction initiates the process of killing of target cell.
After interaction cytotoxic t cell release cytotoxic substance called granzyme and perforin. Granzyme triggers apoptosis through the activation of caspases or by making the release of cytochrome c and activation of the apoptosome.
Perforin make pores in the cell and its action is similar to complement membrane attack complex. Therefore cytotoxic substances are released by Tc cells which trigger apoptosis of target cell.
Based on Le Chatelier's principle, if the equilibrium of a system is disturbed by changing the temperature, pressure or concentration, then it will shift in a direction to undo the effect of the induced change.
The given equilibrium is:
A + B ↔ AB
Removal of the reactant A implies that the concentration of A has decreased, therefore the equilibrium will shift in a direction to produce more of A. Thus, it will shift to the left and the rate of the reverse or backward reaction will increase.
This is a basic orbital diagram for carbon
D. All of the above. Developing medicine, analyzing compounds and producing new product such as plastic all have to deal with chemistry.
