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Alex17521 [72]
3 years ago
6

If a student did not remove all of the bubbles from inside the buret before reading the initial volume and beginning the titrati

on, will this cause the calculated concentration of the hydrochloric acid determined from that trial to be higher or lower than the actual concentration? explain your answer in complete sentences.
Chemistry
1 answer:
matrenka [14]3 years ago
5 0
Hello!

If there's an air bubble inside the buret,  and the bubble escapes the buret during the titration the initial volume lecture (Vi) would be lower (closer to 0) than the actual one, and the recorded consumed volume (ΔV=Vf-Vi) would be higher than the actual one and thus the calculated concentration of the hydrochloric acid would be higher than the real one.

Have a nice day!
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<u>Answer:</u> The correct statement is if you add the soluble salt KA to a solution of HA that is at equilibrium, the pH would increase.

<u>Explanation:</u>

Common ion effect is defined as the effect which occurs on equilibrium when a common ion (an ion which is already present in the solution) is added to a solution. This effect generally decreases the solubility of a solute.

Equilibrium reaction of HA and KA follows the equation:

HA\rightleftharpoons H^{+}(aq.)+A^{-}(aq.)

KA\rightleftharpoons K^+(aq.)+A^{-}(aq.)

According to Le-Chateliers principle, if there is any change in the variables of the reaction, the equilibrium will shift in the direction in order to minimize the effect.

In the equilibrium reactions, A^- ion is getting increased on the product side, so the equilibrium will shift in the direction to minimize this effect, which is in the direction of HA.

Thus, the addition of KA will shift the equilibrium in the left direction.

Equilibrium constant depends on the temperature of the system. It does not have any effect on any change of pH.

pH is defined as the negative logarithm of hydrogen ions present in the solution

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As, the equilibrium is shifting in the left direction, that means concentration of H^+ ions are getting decreases. This will increase the pH of the solution.

Hence, the correct statement is if you add the soluble salt KA to a solution of HA that is at equilibrium, the pH would increase.

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If the process is isothermical the U doesn't change:

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