The longest hydrocarbon chain in the given compound is hexane, therefore it is the parent chain to be considered with one methyl group attached to the 3rd carbon and one chloro attached on the 2nd carbon, therefore the name of the compound is 2-chloro-3-methylhexane
Since the water is at 100 degrees then it take 40.6 kj/mol to change 1 mole of water at 100 degrees into steam at 100 degrees the moles of water 8.22mol since one mole take 40.6kj/mol 8.22mol will be = 8.22mol x 40.6 kj/mol =333.732 kj