(NH4)2SO4 What is the oxidation number of N?
2 answers:
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Answer:
Pentan-2-ol
Explanation:
On this reaction, we have a <u>Grignard reagent</u> (ethylmagnesium bromide), therefore we will have the production of a <u>carbanion</u> (step 1). Then this carbanion can <u>attack the least substituted carbon</u> in the epoxide in this case carbon 1 (step 2). In this step, the epoxide is open and a negative charge is generated in the oxygen. The next step, is the <u>treatment with aqueous acid</u>, when we add acid the <u>hydronium ion</u> () would be produced, so in the reaction mechanism, we can put the hydronium ion. This ion would be <u>attacked by the negative charge</u> produced in the second step to produce the final molecule: <u>"Pentan-2-ol".</u>
See figure 1
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Answer:
Four possible isomers (1–4) for the natural product essramycin. The structure of compound 1 was attributed to essramycin by 1H NMR, 13C NMR, HMBC, HRMS, and IR experiments.
Explanation:
Three synthetic routes were used to prepare all four compounds (Figure 2A). All three reactions utilize 2-(5-amino-4H-1,2,4-triazol-3-yl)-1-phenylethanone (5) as the precursor, whereas each uses different esters (6–8) to construct the pyrimidinone ring. Isomer 1 was prepared by reaction A, which used triazole 5 and ethyl acetoacetate (6) in acetic acid. This was the reaction used in syntheses of essramycin by the Cooper and Moody laboratories.3,4 Reaction B produced compound 2 (minor product) and compound 3 (major product), which were separated chromatographically. This reaction allowed reagent 5 to react with ethyl 3-ethoxy-2-butenoate (7) in the presence of sodium in methanol, under reflux for 24 h. Compound 4 was prepared by reaction C, which was obtained by reflux of 5 and methyl 2-butynoate (8) in n-butanol.
