Pressure has little effect on the solubility of liquids and solids because they are almost incompressible True.
Liquids and solids show little change in solubility with changes in pressure. As expected, gases increase in solubility with increasing pressure. Henry's Law states that the solubility of a gas in a liquid is directly proportional to the pressure of that gas above the surface of the solution.
External pressure has little effect on liquid and solid solubility. In contrast, the solubility of a gas increases as the partial pressure of the gas above the solution increases.
Solubility is a measure of the concentration of dissolved gas particles in a liquid and is a function of gas pressure. Increasing the gas pressure increases the number of collisions and increases the solubility, and decreasing the pressure decreases the solubility.
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The overall reaction is given by:

The fast step reaction is given as:

The slow step reaction is given as:
(slow step
)
Now, the expression for the rate of reaction of fast reaction is:
![r_{1}=k_{1}[NO][Br_{2}]-k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=r_%7B1%7D%3Dk_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D-k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
The expression for the rate of reaction of slow reaction is:
Slow step is the rate determining step. Thus, the overall rate of formation is the rate of formation of slow reaction as
takes place in this reaction.
The expression of rate of formation is:

=
(1)
Now, consider that the fast step is always is in equilibrium. Therefore, 
![k_{1}[NO][Br_{2}]= k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=k_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D%3D%20k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
![[NOBr_{2}] = \frac{k_{1}}{k_{-1}}[NO][Br_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D%20%3D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D)
Substitute the value of
in equation (1), we get:
![\frac{d(NOBr)}{dt}=k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=%5Cfrac%7Bd%28NOBr%29%7D%7Bdt%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
=![k_{2} \frac{k_{1}}{k_{-1}}[NO][Br_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D%5BNO%5D)
= ![\frac{k_{1}k_{2}}{k_{-1}}[NO]^{2}[Br_{2}]](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7B1%7Dk_%7B2%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D%5BBr_%7B2%7D%5D)
Thus, rate law of formation of
in terms of reactants is given by
.
5.4 M = moles of solute / 1.50 L
<span>Multiply both sides by 1.50 L to isolate moles of solute on the right. </span>
<span>8.1 mol = moles of solute </span>
A) occurs when water is evaporated.
Electric
current passes through a filament of an incandescent bulb, thereby increasing
it temperature. When current flows, it contains electrons through the filament
to produce light. Typically, incandescent light bulb consists
of a glass enclosure that contains tungsten filament. The glass enclosure
contains either a vacuum or an inert gas that serves as the filament protection
from evaporating. Incandescent light bulbs contain a stem attached at to its
base to allow the electrical contacts to run through the envelope without gas
or air leaks.