Answer:
a) K = 5.3175
b) ΔG = 3.2694
Explanation:
a) ΔG° = - RT Ln K
∴ T = 25°C ≅ 298 K
∴ R = 8.314 E-3 KJ/K.mol
∴ ΔG° = - 4.140 KJ/mol
⇒ Ln K = - ( ΔG° ) / RT
⇒ Ln K = - ( -4.140 KJ/mol ) / (( 8.314 E-3 KJ/K.mol )( 298 K ))
⇒ Ln K = 1.671
⇒ K = 5.3175
b) A → B
∴ T = 37°C = 310 K
∴ [A] = 1.6 M
∴ [B] = 0.45 M
∴ K = [B] / [A]
⇒ K = (0.45 M)/(1.6 M)
⇒ K = 0.28125
⇒ Ln K = - 1.2685
∴ ΔG = - RT Ln K
⇒ ΔG = - ( 8.314 E-3 KJ/K.mol )( 310 K )( - 1.2685 )
⇒ ΔG = 3.2694
Answer : The final equilibrium temperature of the water and iron is, 537.12 K
Explanation :
In this problem we assumed that heat given by the hot body is equal to the heat taken by the cold body.
where,
= specific heat of iron = 560 J/(kg.K)
= specific heat of water = 4186 J/(kg.K)
= mass of iron = 825 g
= mass of water = 40 g
= final temperature of water and iron = ?
= initial temperature of iron = 
= initial temperature of water = 
Now put all the given values in the above formula, we get:
Therefore, the final equilibrium temperature of the water and iron is, 537.12 K
Answer: (3) The difference in electronegativity between carbon and oxygen is greater than that between fluorine and oxygen.
Explanation: Polarity of a molecule is due to the difference in electronegativity of the atoms. More is the electronegativity difference, more is the polarity.
Electronegativity of carbon = 2.5
Electronegativity of oxygen = 3.5
Electronegativity of fluorine = 4.0
Thus the difference in electronegativity of carbon and oxygen is=(3.5-2.5)= 1.0
Thus the difference in electronegativity of fluorine and oxygen is=(4.0-3.5)= 0.5.
Thus C-O bond is more polar than F-O bond.
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