Answer:
1. relative time
2.absolute time
Explanation:
Time that is measured in definite periods such as minutes, days, and years is called
a. Relative time.
b. absolute time.
Answer:
1. The product has a higher Rf value on a silica gel TLC plate because it is more polar than the starting methyl benzoate.
2. False
3. True
Explanation:
In chromatography, there is a stationary phase and a mobile phase. The ratio of the distance moved by a component and the distance moved by the solvent gives the retention factor (Rf).
Since silica gel is a polar solvent, it will retain the more polar product methyl m-nitrobenzoate compared to the methyl benzoate starting material.
In comparing the electrophillic aromatic substitution of m-nitrobenzoate and methyl benzoate, we must remember that the presence of electron withdrawing groups (such as -NO2 and -CHO) on the aromatic compound deactivates the compound towards electrophillic aromatic substitution hence, methyl m-nitrobenzoate is less reactive than methyl benzoate in Electrophilic Aromatic Substition and Methyl benzoate is less reactive than benzene in Electrophilic Aromatic Substition
Answer:
A) [H3PO4] will increase, [KH2PO4] will decrease, and pH will slightly decrease.
Explanation:
A buffer is a solution which resists changes to its pH when a small amount of acid or base is added to it.
Buffers consist of a weak acid (HA) and its conjugate base (A–) or a weak base and its conjugate acid. Weak acids and bases do not completely dissociate in water, and instead exist in solution as an equilibrium of dissociated and undissociated species. When a small quantity of a strong acid is added to a buffer solution, the conjugate base, A-, reacts with the hydrogen ions from the added acid to form the weak acid and a salt thereby removing the extra hydrogen ions from the solution and keeping the pH of the solution fairly constant. On the other hand, if a small quantity of a strong base is added to the buffer solution, the weak acid dissociates further to release hydrogen ions which then react with the hydroxide ions of the added base to form water and the conjugate base.
For example, if a small amount of strong acid is added to a buffer solution that is 0.700 M H3PO4 and 0.700 M KH2PO4, the following reaction is obtained:
KH₂PO₄ + H+ ----> K+ + H₃PO₄
Therefore, [H₃PO₄] will increase, [KH₂PO₄] will decrease, and pH will slightly decrease.:
