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Colt1911 [192]
3 years ago
15

The combustion of 1.00 mol of glucose, C6H12O6, releases 2820 kJ of heat. If 2.0 g of glucose is burned in a calorimeter contain

ing 1.0 kg of water, and the temperature increases by 3.5 oC, what is the heat capacity of the calorimeter?
Chemistry
1 answer:
DochEvi [55]3 years ago
3 0

Answer:

The heat capacity of the calorimeter is 4.76 kJ/°C

Explanation:

Step 1: Data given

1.00 mol of glucose releases 2820 kJ of heat

Mass of glucose = 2.0 grams

Mass of water = 1000 grams

The temperature increases with 3.5 °C

Step 2: Calculate moles

moles glucose = mass glucose / molar mass glucose

moles glucose = 2.0 grams / 180.16 g/mol

moles glucose = 0.0111 moles

Step 3: Calculate heat produced by the combustion

Heat produced = 2820 kJ/mol * 0.0111 moles

Heat produced = 31.302 kJ = 31302 J

Step 4: Calculate heat absorbed by the water

Q = m*c*ΔT

⇒ with m = the mass of water = 1000 grams

⇒ with c = the specific heat of water = 4.184 J/g°C

⇒ with ΔT = The change in temperature = 3.5 °C

Q = 1000 * 4.184 *3.5

Q = 14644 J absorbed by the water

Step 5: Calculate heat basorbed by the calorimeter

Q = 31302 - 14644 = 16658 J absorbed by the calorimeter

Step 6: Calculate the heat capacity of the calorimeter

c= 16658 J / 3.5 °C

c = 4759 J/°C = 4.76 kJ/°C

The heat capacity of the calorimeter is 4.76 kJ/°C

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"Write the electron Configuration expected for element 113 and the configurations for the two cations it is most likely to form"
arlik [135]

Answer:

Element:

1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶6s²4f¹⁴5d¹⁰6p⁶7s²5f¹⁴6d¹⁰7p¹

Cations:

1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶6s²4f¹⁴5d¹⁰6p⁶7s²5f¹⁴6d¹⁰

1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶6s²4f¹⁴5d¹⁰6p⁶5f¹⁴6d¹⁰

Explanation:

The electron configuration is the distribution of the electrons in the sublevels in order of the crescent energy of them. The crescent energy of the sublevels follows the Linus Pauling's diagram, which is attached below. The sublevel "s" comports until 2 electrons, the sublevel "p" until 6 electrons, the sublevel "d" until 10 electrons, and sublevel "f" until 14 electrons.

So, for the element with an atomic number of 113, the neutral atom will have 113 electrons:

1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶6s²4f¹⁴5d¹⁰6p⁶7s²5f¹⁴6d¹⁰7p¹

Thus the element is at the 7 period (the highest level), and group 13 (most energic sublevel p with 1 electron), the group of the aluminum. It needs to lose 3 electrons to be stable and follow the octet rule, but the subshells of the last shell are too far away in energetic order, thus, it most probably to lose the electron of 7p and form a monovalent cation, and can lose the two electrons of 7s to form a trivalent cation:

1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶6s²4f¹⁴5d¹⁰6p⁶7s²5f¹⁴6d¹⁰

1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s²4d¹⁰5p⁶6s²4f¹⁴5d¹⁰6p⁶5f¹⁴6d¹⁰

5 0
3 years ago
An ionic bond forms when atoms blank electrons
8_murik_8 [283]

Answer:

An ionic bond forms when atoms transfer electrons.

Explanation:

Ionic bonds are formed when atoms transfer electrons. (In contrast, covalent bonds are formed when atoms share electrons.)

There's a distinction between the two: when two atoms react to form an ionic bond, one atom would completely lose one electron, while the other would completely gain that electron. The atom that loses the electron becomes a positively-charged ion called a cation, whereas the atom that gains the electron becomes a negatively-charged ion called an anion.

For example, consider the reaction between a sodium \rm Na atom and a chlorine \rm Cl atom: \rm Na + Cl \to NaCl.

When the sodium atom and the chlorine atom encounter, the sodium atom would lose one electron to form a positively-charged sodium ion, \rm Na^{+}. The chlorine atom would gain that electron to form a negatively-charged chlorine ion \rm Cl^{-}.

These two ions will readily attract each other because of the opposite electrostatic charges on them. This electrostatic attraction (between two ions of opposite charges) is an ionic bond.

Overall, it would appear as if the sodium \rm Na atom transferred an electron to the chlorine \rm Cl atom to form an ionic bond.

In contrast, when two atoms react to form a covalent bond, they share electrons without giving any away completely. Therefore, it is possible to break certain covalent bonds apart (using a beam of laser, for example) and obtain neutral atoms.

On the other hand, when an ionic bond was broken, the result would be two charged ions- not necessarily two neutral atoms. The electron transfer could not be reversed by simply breaking the bond.

For example, when table salt \rm NaCl is melted (at a very high temperature,) the ionic bond between the sodium ions and chloride ions would (mostly) be broken. However, doing so would only generate a mixture of \rm Na^{+} and \rm Cl^{-} ions- not sodium and chlorine atoms.

7 0
2 years ago
Calculate the energy, in joules, required to ionize a hydrogen atom when its electron is initially in the n =2 energy level. The
qaws [65]

Answer:

E_{ionization}=5.45\times 10^{-19}\ J

Explanation:

E_n=-2.18\times 10^{-18}\times \frac{1}{n^2}\ Joules

For transitions:

Energy\ Difference,\ \Delta E= E_f-E_i =-2.18\times 10^{-18}(\frac{1}{n_f^2}-\frac{1}{n_i^2})\ J=2.18\times 10^{-18}(\frac{1}{n_i^2} - \dfrac{1}{n_f^2})\ J

\Delta E=2.18\times 10^{-18}(\frac{1}{n_i^2} - \dfrac{1}{n_f^2})\ J

So, n_i=2 and n_f=\infty (As the hydrogen has to ionize)

Thus,

\Delta E=2.18\times 10^{-18}(\frac{1}{2^2} - \dfrac{1}{{\infty}^2})\ J

\Delta E=2.18\times 10^{-18}(\frac{1}{2^2})\ J

E_{ionization}=5.45\times 10^{-19}\ J

4 0
3 years ago
Write balanced equations that describe the following reactions. (Use the lowest possible coefficients. Use the pull-down boxes t
Gnesinka [82]

Answer :  The balanced chemical reaction will be:

HBrO_4(aq)+H_2O(l)\rightarrow H_3O^+(aq)+BrO_4^-(aq)

Explanation:

Balanced chemical reaction : It is defined as the reaction in which the number of atoms of individual elements present on reactant side must be equal to the product side.

As we know that perbromic acid is considered a strong acid that means it will completely dissociate in water.

The balanced chemical reaction will be:

HBrO_4(aq)+H_2O(l)\rightarrow H_3O^+(aq)+BrO_4^-(aq)

8 0
3 years ago
Which orbital has the lowest energy
GalinKa [24]

Answer:

s orbital

Explanation:

it has the lowest energy because

Paulis law state that orbitals with lower energy must be fill first before that of higher energy

and the s orbital is filled first

5 0
3 years ago
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