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LUCKY_DIMON [66]
3 years ago
14

A 52.0 mL volume of 0.25 M HBr is titrated with 0.50 M KOH. Calculate the pH after addition of 26.0 mL of KOH at 25 ∘C.

Chemistry
1 answer:
prohojiy [21]3 years ago
7 0
The balanced equation for the above reaction is 
HBr + KOH ---> KBr + H₂O
stoichiometry of HBr to KOH is 1:1
HBr is a strong acid and KOH is a strong base and they both completely dissociate.
The number of HBr moles present - 0.25 M / 1000 mL/L x 52.0 mL = 0.013 mol
The number of KOH moles added - 0.50 M / 1000 mL/L x 26.0 mL  = 0.013 mol
the number of H⁺ ions = number of OH⁻ ions
therefore complete neutralisation occurs. 
Therefore solution is neutral. At 25 °C, when the solution is neutral, pH = 7.
Then pH of solution is 7
 
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<u>Answer:</u> The value of K_{eq} is 0.044

<u>Explanation:</u>

We are given:

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Volume of the container = 1.00 L

Concentration of a substance is calculated by:

\text{Concentration}=\frac{\text{Number of moles}}{\text{Volume}}

So, concentration of methane = \frac{0.0410}{1.00}=0.0410M

Concentration of carbon tetrachloride = \frac{0.0651}{1.00}=0.0651M

The given chemical equation follows:

                    CH_4(g)+CCl_4(g)\rightleftharpoons 2CH_2Cl_2(g)

<u>Initial:</u>          0.0410    0.0651

<u>At eqllm:</u>     0.0410-x   0.0651-x       2x

We are given:

Equilibrium concentration of carbon tetrachloride = 6.02\times 10^{-2}M=0.0602M

Evaluating the value of 'x', we get:

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Now, equilibrium concentration of methane = 0.0410-x=[0.0410-0.0049]=0.0361M

Equilibrium concentration of CH_2Cl_2=2x=[2\times 0.0049]=0.0098M

The expression of K_{eq} for the above reaction follows:

K_{eq}=\frac{[CH_2Cl_2]^2}{[CH_4]\times [CCl_4]}

Putting values in above expression, we get:

K_{eq}=\frac{(0.0098)^2}{0.0361\times 0.0603}\\\\K_{eq}=0.044

Hence, the value of K_{eq} is 0.044

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