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Jet001 [13]
3 years ago
14

Given following electron configurations, 1s22s22p63s23p64s23d104p65s24d9 and 1s22s22p63s23p64s23d104p65s14d10.

Chemistry
1 answer:
marusya05 [52]3 years ago
8 0

Explanations:- Part 1: We could count the total number of electrons by looking at the electron configurations. Both of these electrons configurations have 47 electrons. If we look at the periodic table then 47 is the atomic number of silver. So, the name of the element is silver and its represented as Ag.

Part 2: As per the rule, Completely filled and half filled orbitals are more stable. First electron configuration has 9 electrons in 4d and we know that d is more stable if it has 5 electrons(half filled) or it has 10 electrons(full filled).

For stability reasons, one of the electron from 5s goes to 4d and for this reason the second electron configuration is found most often in nature for silver.

Few other examples are Cr and Cu.

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When 1.2383 g of an organic iron compound containing Fe, C, H, and O was burned in O2, 2.3162 g of CO2 and 0.66285 g of H2O were
uysha [10]

Answer:

\boxed{\text{C$_{15}$H$_{21}$FeO$_{6}$}}

Explanation:

Let's call the unknown compound X.

1. Calculate the mass of each element in 1.23383 g of X.

(a) Mass of C

\text{Mass of C} = \text{2.3162 g } \text{CO}_{2}\times \dfrac{\text{12.01 g C}}{\text{44.01 g }\text{CO}_{2}}= \text{0.632 07 g C}

(b) Mass of H

\text{Mass of H} = \text{0.66285 g }\text{H$_{2}$O}\times \dfrac{\text{2.016 g H}}{\text{18.02 g } \text{{H$_{2}$O}}} = \text{0.074 157 g H}

(c)Mass of Fe

(i)In 0.4131g of X

\text{Mass of Fe} = \text{0.093 33 g Fe$_{2}$O$_{3}$}\times \dfrac{\text{111.69 g Fe}}{\text{159.69 g g Fe$_{2}$O$_{3}$}} = \text{0.065 277 g Fe}

(ii) In 1.2383 g of X

\text{Mass of Fe} = \text{0.065277 g Fe}\times \dfrac{1.2383}{0.4131} = \text{0.195 67 g Fe}

(d)Mass of O

Mass of O = 1.2383 - 0.632 07 - 0.074 157 - 0.195 67 = 0.336 40 g

2. Calculate the moles of each element

\text{Moles of C = 0.63207 g C}\times\dfrac{\text{1 mol C}}{\text{12.01 g C }} = \text{0.052 629 mol C}\\\\\text{Moles of H = 0.074157 g H} \times \dfrac{\text{1 mol H}}{\text{1.008 g H}} = \text{0.073 568 mol H}\\\\\text{Moles of Fe = 0.195 67 g Fe} \times \dfrac{\text{1 mol Fe}}{\text{55.845 g Fe}} = \text{0.003 5038 mol Fe}\\\\\text{Moles of O = 0.336 40} \times \dfrac{\text{1 mol O}}{\text{16.00 g O}} = \text{0.021 025 mol O}

3. Calculate the molar ratios

Divide all moles by the smallest number of moles.

\text{C: } \dfrac{0.052629}{0.003 5038}= 15.021\\\\\text{H: } \dfrac{0.073568}{0.003 5038} = 20.997\\\\\text{Fe: } \dfrac{0.003 5038}{0.003 5038} = 1\\\\\text{O: } \dfrac{0.021025}{0.003 5038} = 6.0006

4. Round the ratios to the nearest integer

C:H:O:Fe = 15:21:1:6

5. Write the empirical formula

\text{The empirical formula is } \boxed{\textbf{C$_{15}$H$_{21}$FeO$_{6}$}}

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Answer:

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Explanation:

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