Use the data in the table above to calculate an approximate ΔH∘ in kilojoules for the synthesis of hydrazine from ammonia:
1 answer:
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Explanation:
Part a
Pyridine is an aromatic heterocyclic compound and undergoes nucleophilic aromatic substitution reaction at 2 and 4 positions.
This is because, when a nucleophile attack pyridine at 2 and 4 positions, the anoin formed is stabilized. In the anion formed is tabilized by resonance and also negative charge is present at electronegative atom, nitrogen.
If the nucleophile attack at 3 position, the anion formed is not as stable as anions formed when nucleophile attach at 2 and 4 positions. This is because negative charge is not present at the nitrogen atom.
Part b:
Tautomers are structural isomers of each others formed by migration atom within the molecule. Tautomers exist in equilibrium with each other.
Tautomers of 2-Hydroxypyridine and 4-Hydroxypyrine are given in the attachment.
Answer:
Solution A that will form a precipitate with Ksp = 2.3 x 10−4
Explanation:
Li₃PO₄ ⇄ 3 Li⁺(aq) + PO₄³⁻(aq)
3S S
Where S = Solubility(mole/lit) and Ksp = Solubility product
⇒ Ksp = (3S)³ x (S)
⇒ 27S⁴ = 2.3x10−4
⇒ S = 0.05 mol/lit
Concentration of Li₃PO₄ precipitate = 0.05
<u>Solution A </u>
0.500 lit of a 0.3 molar LiNO₃ contains 0.5 x 0.3 = 0.15 mole
0.4 lit of a 0.2 molar Na₃PO₄ contains = 3 x 0.4 x 0.2 = 0.24 mole
3 LiNO₃ + Na₃PO₄ → 3 NaNO₃ + Li₃PO₄
(Mole/Stoichiometry)
= 0.05 = 0.24
Since from (Mole/Stoichiometry) ratio we can conclude that LiNO₃ is limiting reagent.
So concentration of Li₃PO₄ is equal to 0.05.