Correct answer is <span>X = ΔH
Reason:
1) The graph of enthalpy Vs reaction coordinate suggest the reaction is endothermic in nature. For endothermic reaction, energy if product is more than that of reactant. Hence, option 1 i.e. </span><span>X = -ΔH cannot be correct.
2) Since the reaction is endothermic in nature, </span>energy if product is more than that of reactant. Hence, option 2 i.e. X = ΔH is correct.
3) Activation energy is energy difference between Reactant (A) and transition state (B). However, as per option C, activation energy (A.E.) is energy difference between product (C) and transition state (B), which is incorrect.
Answer:
1.62
Explanation:
From the given information:
number of moles of benzamide
= 0.58 mole
The molality =
= 0.6837
Using the formula:
where;
dT = freezing point = 27
l = Van't Hoff factor = 1
kf = freezing constant of the solvent
∴
2.7 °C = 1 × kf × 0.6837 m
kf = 2.7 °C/ 0.6837m
kf = 3.949 °C/m
number of moles of NH4Cl =
= 1.316 mol
The molality =
= 1.5484
Thus;
the above kf value is used in determining the Van't Hoff factor for NH4Cl
i.e.
9.9 = l × 3.949 × 1.5484 m
l = 1.62