q = mCΔT
The correct specific heat capacity of water is <em>4.187 kJ/(kg.K)</em>.
ΔT = q/mC = 87 kJ/[648.00 kg x 4.187 kJ/(kg.K)] = 87 kJ/(2713 kJ/K) = 0.032 K
Tf = Ti + ΔT = 298 K + 0.032 K = 298.032 K
Answer:
Here's what I get
Explanation:
You may have done a Williamson synthesis of guaifenesin by reacting guaiacol with 3-chloropropane-1,2-diol.
A. Mechanism
Step 1
NaOH converts guaiacol into a phenoxide ion.
Step 2
The phenoxide acts as the nucleophile in an SN2 reaction to displace the Cl from the alkyl halide.
B. Improve the yield
You probably carried out the reaction in ethanol solution — a polar protic solvent.
You might try doing the reaction in a polar aprotic solvent— perhaps DMSO.
A polar aprotic solvent does not hydrogen bond to nucleophiles, so they become stronger.
C. Another method of ether synthesis —dehydration of alcohols
Sulfuric acid catalyzes the conversion of primary alcohols to ethers.
This is also a nucleophilic displacement reaction.
Protonation of the OH converts it into a better leaving group.
Attack by a second molecule of alcohol forms the protonated ether.
A molecule of water then removes the proton.
Answer:
<u><em>See attachment for explanations.</em></u>
Explanation:
So its temperature will not rise, since kinetic energy of molecules remains the same. The quantity of heat absorbed or released when a substance changes its physical phase at constant temperature (e g. From solid to liquid at melting point or from liquid to gas at boiling point) is termed as its latent heat.