Answer:
there are four peaks in the 13c NMR (B)
The rate of disappearance of chlorine gas : 0.2 mol/dm³
<h3>Further explanation</h3>
The reaction rate (v) shows the change in the concentration of the substance (changes in addition to concentrations for reaction products or changes in concentration reduction for reactants) per unit time.
For reaction :
The rate reaction :
![\tt -\dfrac{1}{a}\dfrac{d[-A]}{dt}= -\dfrac{1}{b}\dfrac{d[-B]}{dt}=\dfrac{1}{c}\dfrac{d[C]}{dt}=\dfrac{1}{d}\dfrac{d[D]}{dt}](https://tex.z-dn.net/?f=%5Ctt%20-%5Cdfrac%7B1%7D%7Ba%7D%5Cdfrac%7Bd%5B-A%5D%7D%7Bdt%7D%3D%20-%5Cdfrac%7B1%7D%7Bb%7D%5Cdfrac%7Bd%5B-B%5D%7D%7Bdt%7D%3D%5Cdfrac%7B1%7D%7Bc%7D%5Cdfrac%7Bd%5BC%5D%7D%7Bdt%7D%3D%5Cdfrac%7B1%7D%7Bd%7D%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D)
Reaction for formation CCl₄ :
<em>CH₄+4Cl₂⇒CCl₄+4HCl</em>
<em />
From equation, rate of reaction = rate of formation CCl₄ = 0.05 mol/dm³
Rate of formation of CCl₄ = reaction rate x coefficient of CCCl₄
0.05 mol/dm³ = reaction rate x 1⇒reaction rate = 0.05 mol/dm³
The rate of disappearance of chlorine gas (Cl₂) :
Rate of disappearance of Cl₂ = reaction rate x coefficient of Cl₂
Rate of disappearance of Cl₂ = 0.05 x 4 = 0.2 mol/dm³
Answer:
Kc = 1.09x10⁻⁴
Explanation:
<em>HF = 1.62g</em>
<em>H₂O = 516g</em>
<em>F⁻ = 0.163g</em>
<em>H₃O⁺ = 0.110g</em>
<em />
To solve this question we need to find the moles of each reactant in order to solve the molar concentration of each reactan and replacing in the Kc expression. For the reaction, the Kc is:
Kc = [H₃O⁺] [F⁻] / [HF]
<em>Because Kc is defined as the ratio between concentrations of products over reactants powered to its reaction coefficient. Pure liquids as water are not taken into account in Kc expression:</em>
<em />
[H₃O⁺] = 0.110g * (1mol /19.01g) = 0.00579moles / 5.6L = 1.03x10⁻³M
[F⁻] = 0.163g * (1mol /19.0g) = 0.00858moles / 5.6L = 1.53x10⁻³M
[HF] = 1.62g * (1mol /20g) = 0.081moles / 5.6L = 0.0145M
Kc = [1.03x10⁻³M] [1.53x10⁻³M] / [0.0145M]
<h3>Kc = 1.09x10⁻⁴</h3>
We can use the ideal gas equation:
PV = nRT
P = 202.6kPa = 202600 Pa (You have to
multiply by 1000)
n = 0.050 mole
R = 0.082 atm*l/(K*mol)
T = 400K
We will have to convert from Pa to atm or
viceversa.
101325 Pa________1 atm
202600 Pa________x = 2.00 atm
2atm*V = 0.050 mole*0.082 atm*l/(K*mol)* 400K
V = 0.050 mole*0.082 atm*l/(K*mol)* 400K/2atm
= 0.82 liters = 820 mililiters
