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Answer : Option 1) The true statement is each carbon-oxygen bond is somewhere between a single and double bond and the actual structure of format is an average of the two resonance forms.
Explanation : The actual structure of formate is found to be a resonance hybrid of the two resonating forms. The actual structure for formate do not switches back and forth between two resonance forms.
The O atom in the formate molecule with one bond and three lone pairs, in the resonance form left with reference to the attached image, gets changed into O atom with two bonds and two lone pairs.
Again, the O atom with two bonds and two lone pairs on the resonance form left, changed into O atom with one bond and three lone pairs. It concludes that each carbon-oxygen bond is neither a single bond nor a double bond; each carbon-oxygen bond is somewhere between a single and double bond.
Also, it is seen that each oxygen atom does not have neither a double bond nor a single bond 50% of the time.
Answer: The osmotic pressure of a solution is 53.05 atm
Explanation:
To calculate the concentration of solute, we use the equation for osmotic pressure, which is:
Or,
where,
= osmotic pressure of the solution = ?
i = Van't hoff factor = 1 (for non-electrolytes)
Mass of solute (methanol) = 22.3 g
Volume of solution = 321 mL
R = Gas constant =
T = temperature of the solution =
Putting values in above equation, we get:
Hence, the osmotic pressure of a solution is 53.05 atm