Answer :
The concentration of
before any titrant added to our starting material is 0.200 M.
The pH based on this
ion concentration is 0.698
Explanation :
First we have to calculate the concentration of
before any titrant is added to our starting material.
As we are given:
Concentration of HBr = 0.200 M
As we know that the HBr is a strong acid that dissociates complete to give hydrogen ion
and bromide ion
.
As, 1 M of HBr dissociates to give 1 M of 
So, 0.200 M of HBr dissociates to give 0.200 M of 
Thus, the concentration of
before any titrant added to our starting material is 0.200 M.
Now we have to calculate the pH based on this
ion concentration.
pH : It is defined as the negative logarithm of hydrogen ion concentration.
![pH=-\log [H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH%5E%2B%5D)


Thus, the pH based on this
ion concentration is 0.698
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Hope i helped... If you need anything else ask me! :)