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Gennadij [26K]
4 years ago
5

A 200.0mL flask of unknown gas was placed in a hot water bath. The temperature of the bath was found to be 99 degrees C. The pre

ssure of the flask was 733mmHg. The flask with the unknown gas in it had a mass of 126.593g. The same flask weighed 125.623g when it was empty. Determine the mass f the unknown gas in the flask. Determine the Molar Mass of an unknown gas. (Assume that the Ideal Gas Law is obeyed and use R= 0.0821 L atm/mol K SHOW ALL WORK.)
Chemistry
1 answer:
masya89 [10]4 years ago
8 0
A. Mass of the unknown gas.

The mass of the unknown gas is calculated by subtracting the weight of the empty flask from the mass when there was air in it.

      m = 126.593 g - 125.623 g

Simplifying,
     m = 0.97 grams

b. Molar mass of the gas
The molar mass of the gas is calculated by the ideal gas law.

                PV = (m/M)RT

where P is pressure,V is volume, m is the mass, M is the molar mass, R is the universal gas constant, and T is temperature. Substituting the known values to the equation,

     (733 mmHg/760 mmHg/atm)(0.20 L) = (0.97 g/M)(0.0821 L.atm/molK)(99 + 273.15 K)

The value of M in the equation is 153.64 g/mol.

<em>Answer: 153.64 g/mol</em>

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Answer:

0.031 parts per million

Explanation:

80 micrograms/m^3 = 80 micrograms/m^3 × 1m^3/1000L = 0.08 micrograms/L

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Concentration in micrograms/L = 0.08

Molar volume at 25°C and 101.325kPa (1 atm) is 24.45L

MW of SO2 = 64g/mole

Concentration in ppm = 0.08×24.45/64 = 0.031 ppm

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<u>Answer:</u> The total number of electrons that must be shared between carbon and oxygen atoms are 8.

<u>Explanation:</u>

A covalent compound is formed when sharing of electrons takes place between the atoms forming a compound.

Carbon is the 6th element of the periodic table having electronic configuration of 1s^22s^22p^2

This element requires 4 electrons to complete its shell.

Oxygen is the 8th element of the periodic table having electronic configuration of 1s^22s^22p^4

This element requires 2 electrons to complete its shell.

So, in order to complete the octet of both the elements, 2 oxygen atoms are required for 1 carbon atom.

Hence, the total number of electrons that must be shared between carbon and oxygen atoms are 8.

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Consider the following multistep reaction:
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The question is incomplete, here is the complete question:

Consider the following multistep reaction:

C+D⇌CD (fast)

CD+D→CD₂ (slow)

CD₂+D→CD₃ (fast)

C+3D→CD₃

Based on this mechanism, determine the rate law for the overall reaction.

<u>Answer:</u> The rate law for the reaction is \text{Rate}=k'[C][D]^2

<u>Explanation:</u>

Rate law is the expression which is used to express the rate of the reaction in terms of the molar concentration of reactants where each term is raised to the power their stoichiometric coefficient respectively from a balanced chemical equation.

In a mechanism of the reaction, the slow step in the mechanism determines the rate of the reaction.

For the given chemical reaction:

C+3D\rightarrow CD_3

The intermediate reaction of the mechanism follows:

<u>Step 1:</u>  C+D\rightleftharpoons CD;\text{ (fast)}

<u>Step 2:</u>  CD+D\rightarrow CD_2;\text{(slow)}

<u>Step 3:</u>  CD_2+D\rightarrow CD_3;\text{(fast)}

As, step 2 is the slow step. It is the rate determining step

Rate law for the reaction follows:

\text{Rate}=k[CD][D]           ......(1)

As, [CD] is not appearing as a reactant in the overall reaction. So, we apply steady state approximation in it.

Applying steady state approximation for CD from step 1, we get:

K=\frac{[CD]}{[C][D]}

[CD]=K[C][D]

Putting the value of [CD] in equation 1, we get:

\text{Rate}=k.K[C][D]^2\\\\\text{Rate}=k'[C][D]^2  

Hence, the rate law for the reaction is \text{Rate}=k'[C][D]^2

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