Boyle found that when the pressure of gas at a constant temperature is increased, the volume of the gas decreases. when the pressure of gas is decreased, the volume increases. this relationship between pressure and volume is called Boyle's law.
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Based upon Max Planck's theory of black-body radiation, Einstein theorized that the energy in each quantum of light was equal to the frequency multiplied by a constant, later called Planck's constant. A photon above a threshold frequency has the required energy to eject a single electron, creating the observed effect.