The breaking of chemical bonds never releases energy to the external environment. Energy is only released when chemical bonds are formed. In general, a chemical reaction involves two steps: 1) the original chemical bonds between the atoms are broken, and 2) new bonds are formed. These two steps are sometimes lumped into one event for simplicity, but they are really two separate events. For instance, when you burn methane (natural gas) in your stove, the methane is reacting with oxygen to form carbon dioxide and water.
This is the temperature indicated by a moistened thermometer bulb exposed to the air flow. The evaporation is reduced when the air contains more water vapor. The wet bulb temperature is always lower than the dry bulb temperature but will be identical with 100% relative humidity.