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KatRina [158]
3 years ago
8

When 50 ml of 1.000x10^-1m pb(no3)2 solution was added to 50 ml of 1.000x10^-1m nai solution?

Chemistry
1 answer:
podryga [215]3 years ago
3 0

Balanced chemical reaction: Pb(NO₃)₂ (aq) + 2NaI(aq) → 2PbI₂(s) + 2NaNO₃(aq).

V(Pb(NO₃)₂) = 50 mL ÷ 1000 mL = 0.05 L, volume of solution.

c(Pb(NO₃)₂) = 0.1 mol/L; concentration of solution.

n(Pb(NO₃)₂) = c(Pb(NO₃)₂) · V(Pb(NO₃)₂).

n(Pb(NO₃)₂) = 0.1 mol/L · 0.05 L.

n(Pb(NO₃)₂) = 0.005 mol.

n(NaI) = c(NaI) · V(NaI).

n(NaI) = 0.1 mol/L · 0.05 L.

n(NaI) = 0.005 mol; amount of substance.

From chemical reaction: n(Pb(NO₃)₂) : n(NaI) = 1 : 2.

n(Pb(NO₃)₂) = 0.005 mol ÷ 2.

n(Pb(NO₃)₂) = 0.0025 mol; number of moles Pb(NO₃)₂ used.

n(NaI) = 0.005 mol; number of moles NaI used.

The limiting reagent is Pb(NO₃)₂.

n(PbI₂) = 0.005 mol.

m(PbI₂) = n(PbI₂) · M(PbI₂).

m(PbI₂) = 0.005 mol · 461 g/mol.

m(PbI₂) = 2.305 g; the theoretical yield of PbI₂.

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Method One: Refer to electron transfers.

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  • Fe: from +3 to 0; gains three electrons.

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? Na + <em>1</em> Fe₂O₃ → ? Na₂O + ? Fe

There are two moles of Fe atoms and three moles of O atoms in each mol of Fe₂O₃. One mole of Fe₂O₃ contains two moles of Fe and three moles of O. There are one mole of O atom in every mole of Na₂O. Three moles of O will go to three moles of Na₂O.

? Na + <em>1</em> Fe₂O₃ → <em>3</em> Na₂O + <em>2</em> Fe

Each mole of Na₂O contains two moles of Na. Three moles of Na₂O will contain six moles of Na.

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Simplify the coefficients. All coefficients in this equation are now full number and relatively prime. Hence the equation is balanced.

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