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KatRina [158]
3 years ago
8

When 50 ml of 1.000x10^-1m pb(no3)2 solution was added to 50 ml of 1.000x10^-1m nai solution?

Chemistry
1 answer:
podryga [215]3 years ago
3 0

Balanced chemical reaction: Pb(NO₃)₂ (aq) + 2NaI(aq) → 2PbI₂(s) + 2NaNO₃(aq).

V(Pb(NO₃)₂) = 50 mL ÷ 1000 mL = 0.05 L, volume of solution.

c(Pb(NO₃)₂) = 0.1 mol/L; concentration of solution.

n(Pb(NO₃)₂) = c(Pb(NO₃)₂) · V(Pb(NO₃)₂).

n(Pb(NO₃)₂) = 0.1 mol/L · 0.05 L.

n(Pb(NO₃)₂) = 0.005 mol.

n(NaI) = c(NaI) · V(NaI).

n(NaI) = 0.1 mol/L · 0.05 L.

n(NaI) = 0.005 mol; amount of substance.

From chemical reaction: n(Pb(NO₃)₂) : n(NaI) = 1 : 2.

n(Pb(NO₃)₂) = 0.005 mol ÷ 2.

n(Pb(NO₃)₂) = 0.0025 mol; number of moles Pb(NO₃)₂ used.

n(NaI) = 0.005 mol; number of moles NaI used.

The limiting reagent is Pb(NO₃)₂.

n(PbI₂) = 0.005 mol.

m(PbI₂) = n(PbI₂) · M(PbI₂).

m(PbI₂) = 0.005 mol · 461 g/mol.

m(PbI₂) = 2.305 g; the theoretical yield of PbI₂.

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How many grams of Pb are contained in a mixture of 0.135 kg each of PbCl(OH) and Pb2Cl2CO3?
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Hey there!:

Given the mass of PbCl(OH) :

0.135 Kg = 0.135 Kg*(1000g / 1Kg)  = 135 g

Molecular mass of PbCl(OH)  = 207+35.5+16+1  = 259.5 g / mol

Atomic mass of Pb = 207 g/mol

Hence mass of Pb in 135 g  PbCl(OH)  :

(207 g Pb /  259.5 g PbClOH) * 135g PbClOH  =

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For Pb2Cl2CO3  :

Given the mass of Pb2Cl2CO3  :

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Molecular mass of Pb2Cl2CO3  = 2*207+2*35.5+12+3*16  = 545 g / mol

Mass of Pb present in 1 mol (=545 g / mol) of Pb2Cl2CO3  = 2*207 = 414 g

Hence mass of Pb in 135 g  Pb2Cl2CO3:

(414 g Pb /  545 g PbClOH) * 135g PbClOH  =

0.75963 * 135 => 102.55 g of Pb2Cl2CO3


Hope that helps!

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