Calculate the change in ph when 3.00 ml of 0.100 m hcl(aq) is added to 100.0 ml of a buffer solution that is 0.100 m in nh3(aq)
and 0.100 m in nh4cl(aq). a list of ionization constants can be found here.
1 answer:
The change in pH is calculated by:
pOH = Protein kinase B + log [NH4+]/ [NH3]
Protein kinase B of ammonia = 4.74
initial potential of oxygen hydroxide= 4.74 + log 0.100/0.100 = 4.74
pH = 14 - 4.74=9.26
moles NH4+ = moles NH3 = 0.100 L x 0.100 M = 0.0100
moles H+ added = 3.00 x 10^-3 L x 0.100 M=0.000300
NH3 + H+ = NH4+
moles NH3 = 0.0100 - 0.000300=0.00970
moles NH4+ = 0.0100 + 0.000300=0.0103
pOH = 4.74 + log 0.0103/ 0.00970= 4.77
oH = 14 - 4.77 = 9.23
the change is = 9.26 - 9.23 =0.03
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