Cysteine and methionine contain sulfur.
When mixture of NaCl and Al₂(SO₄)₃ is allowed to react with excess NaOH, only Al₂(SO₄)₃ reacts with it and NaCl does not react with NaOH due to presence of common ion (Na⁺). On reaction gelatinous precipitate of aluminium hydroxide [Al(OH)₃] is produced. The balanced chemical reaction is represented as-
Al₂(SO₄)₃ + 6NaOH → 2Al(OH)₃ + 3Na₂SO₄
On this reaction, 0.495 g = 0.495/78 moles =6.346 X 10⁻³ moles of Al(OH)₃.
As per balanced reaction, two moles of Al(OH)₃ is produced from one mole Al₂(SO₄)₃. So, 6.346 X 10⁻³ moles of Al(OH)₃ is produced from (6.346 X 10⁻³)/2 moles=3.173 X 10⁻³ moles of Al₂(SO₄)₃= 3.173 X 10⁻³ X 342 g of Al₂(SO₄)₃=1.085 g of Al₂(SO₄)₃.
So, mass percentage of Al₂(SO₄)₃ is= (amount of Al₂(SO₄)₃/total amount of mixture)X100 =
=74.8 %.
Answer:
b) add 130 g of NaCH₃CO₂ to 100 mL of H₂O at 80 °C while stirring until all the solid dissolves, then let the solution cool to room temperature.
Explanation:
The solubility of NaCH₃CO₂ in water is ~1.23 g/mL. This means that at room temperature, we can dissolve 1.23 g of solute in 1 mL of water (solvent).
<em>What would be the best method for preparing a supersaturated NaCH₃CO₂ solution?</em>
<em>a) add 130 g of NaCH₃CO₂ to 100 mL of H₂O at room temperature while stirring until all the solid dissolves.</em> NO. At room temperature, in 100 mL of H₂O can only be dissolved 123 g of solute. If we add 130 g of solute, 123 g will dissolve and the rest (7 g) will precipitate. The resulting solution will be saturated.
<em>b) add 130 g of NaCH₃CO₂ to 100 mL of H₂O at 80 °C while stirring until all the solid dissolves, then let the solution cool to room temperature. </em>YES. The solubility of NaCH₃CO₂ at 80 °C is ~1.50g/mL. If we add 130 g of solute at 80 °C and let it slowly cool (and without any perturbation), the resulting solution at room temperature will be supersaturated.
<em>c) add 1.23 g of NaCH₃CO₂ to 200 mL of H₂O at 80 °C while stirring until all the solid dissolves, then let the solution cool to room temperature.</em> NO. If we add 1.23 g of solute to 200 mL of water, the resulting solution will have a concentration of 1.23 g/200 mL = 0.00615 g/mL, which represents an unsaturated solution.
4.92 grams / 6 mL = .82 grams / mL
<span>(A) 0.82 g/mL</span>