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viktelen [127]
4 years ago
11

One of the half-reactions for the electrolysis of water is 2H+(aq) + 2e− → H2(g) If 0.845 L of H2 is collected at 25°C and 782 m

mHg, how many faradays of electricity had to pass through the solution?
Chemistry
1 answer:
DENIUS [597]4 years ago
8 0

0.0725 faradays of electricity had to be passed through the solution.

Explanation:

Find how many hydrogen moles are produced.

1 mole of any gas consumes 24 liters at room temperature  

atmospheric pressure 1 environment is 760 mm Hg  

temperature is 25 deg C  

so if you reduced the pressure down to 760 mm Hg on that 0.845 liters you've gathered, you would discover the volume expanded to  

0.845 x 782/760 = 0.869 liters  

which equals to 0.0362 moles (divide by 24)  

since every atom of hydrogen required 2 electrons to be made, hence we need 0.0725 moles of electrons or 0.0725 faradays.

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aleksklad [387]
<h2>H_2O  + H_2 + O_2</h2>

Explanation:

1. Water decomposition

  • Decomposition reactions are represented by-

       The general equation: AB → A + B.

  • Various methods used in the decomposition of water are -
  1. Electrolysis
  2. Photoelectrochemical water splitting
  3. Thermal decomposition of water
  4. Photocatalytic water splitting
  • Water decomposition is the chemical reaction in which water is broken down giving oxygen and hydrogen.
  • The chemical equation will be -

        H_2O  + H_2 + O_2

Hence, balancing the equation we need to add a coefficient of 2 in front of H_2O on right-hand-side of the equation and  2 in front of H_2 on left-hand-side of the equation.

     ∴The balanced equation is -

       2 H_2O → 2 H_2 + O_2

2. Formation of ammonia

  • The formation of ammonia is by reacting nitrogen gas and hydrogen gas.

      N_2 + H → NH_3

Hence, for balancing equation we need to add a coefficient of 3 in front of hydrogen and 2 in front of ammonia.

   ∴The balanced chemical equation for the formation of ammonia gas is as  follows -

     N_2+3H→ 2NH_3.

  • When 6 moles of N_2 react with 6 moles ofH_2 4 moles of ammonia are produced.

5 0
3 years ago
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