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bixtya [17]
3 years ago
11

Which of the following is not a property of a buffer solution? a) It is a mixture of a weak acid and its conjugate base. b) Resi

sts pH changes because it reacts with added acid or base. c) The maximum buffer capacity is at pH = pKa. d) pH is dependent on the solution ionic strength and temperature. e) pH is independent of concentration.
Chemistry
1 answer:
m_a_m_a [10]3 years ago
8 0

Answer:

e) pH is independent of concentration.

Explanation:

a) It is a mixture of a weak acid and its conjugate base. <em>TRUE. </em>A buffer is defined as a mixture of a weak acid and its conjugate base or a weak base and its conjugate acid.

b) Resists pH changes because it reacts with added acid or base. <em>TRUE. </em>Thermodynamically, the reaction of added acid or base is faster with the buffer mixture than with H⁺ or OH⁻ ions of the solutions.

c) The maximum buffer capacity is at pH = pKa. <em>TRUE. </em>The buffer capacity is pka±1. For this, buffer capacity is maximum in pka.

d) pH is dependent on the solution ionic strength and temperature. <em>TRUE.</em> Ionic strength and temperature are factors that influence concentrations of ions in solutions as the H⁺ ion that is the responsible

e) pH is independent of concentration. <em>FALSE. </em>pH in a buffer depends completely of concentrations of the acid and its conjugate base or vice versa.

I hope it helps!

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A 20.0-milliliter sample of 0.200 M K2CO3 solution is added to 30.0 milliliters of 0.400 M Ba(NO3)2 solution.
jenyasd209 [6]

Answer:

(B) 0.160 M

Explanation:

Considering:

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

Or,

Moles =Molarity \times {Volume\ of\ the\ solution}

Given :

For K_2CO_3 :

Molarity = 0.200 M

Volume = 20.0 mL

The conversion of mL to L is shown below:

1 mL = 10⁻³ L

Thus, volume = 20.0×10⁻³ L

Thus, moles of K_2CO_3 :

Moles=0.200 \times {20.0\times 10^{-3}}\ moles

Moles of K_2CO_3 = 0.004 moles

For Ba(NO_3)_2 :

Molarity = 0.400 M

Volume = 30.0 mL

The conversion of mL to L is shown below:

1 mL = 10⁻³ L

Thus, volume =30.0×10⁻³ L

Thus, moles of Ba(NO_3)_2 :

Moles=0.400\times {30.0\times 10^{-3}}\ moles

Moles of Ba(NO_3)_2  = 0.012 moles

According to the given reaction:

K_2CO_3_{(aq)}+Ba(NO_3)_2_{(aq)}\rightarrow BaCO_3_{(s)}+2KNO_3_{(aq)}

1 mole of potassium carbonate react with 1 mole of barium nitrate

0.004 moles potassium carbonate react with 0.004 mole of barium nitrate

Moles of barium nitrate  = 0.004 moles

Available moles of barium nitrate  =  0.012 moles

Limiting reagent is the one which is present in small amount. Thus, potassium carbonate is limiting reagent.

The formation of the product is governed by the limiting reagent. So,

1 mole of potassium carbonate gives 1 mole of barium carbonate

Also,

0.004 mole of potassium carbonate gives 0.004 mole of barium carbonate

Mole of barium carbonate = 0.004 moles

Also, consumed barium nitrate = 0.004 moles  (barium ions precipitate with carbonate ions)

Left over moles = 0.012 - 0.004 moles = 0.008 moles

Total volume = 20.0 + 30.0 mL = 50.0 mL = 0.05 L

So, Concentration = 0.008/0.05 M = 0.160 M

<u>(B) is correct.</u>

4 0
3 years ago
A 3.82L balloon filled with gas is warmed from 204.9K to 304.8 K.
likoan [24]

Given :

A 3.82L balloon filled with gas is warmed from 204.9K to 304.8 K.

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Solution :

Since, their is no information about pressure in the question statement let us assume that pressure is constant.

Now, we know by ideal gas equation at constant pressure :

\dfrac{V_1}{V_2} = \dfrac{T_1}{T_2}\\\\\dfrac{3.82}{V_2}= \dfrac{204.9}{304.8}\\\\V_2 = \dfrac{304.8}{204.9} \times 3.82\\\\V_2 = 5.68 \ L

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