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abruzzese [7]
3 years ago
11

Question 17 A sample of iron is put into a calorimeter (see sketch at right) that contains of water. The iron sample starts off

at and the temperature of the water starts off at . When the temperature of the water stops changing it's . The pressure remains constant at . Calculate the specific heat capacity of iron according to this experiment. Be sure your answer is rounded to the correct number of significant digits.

Physics
1 answer:
ivanzaharov [21]3 years ago
4 0

Complete Question:

A 59.1 g sample of iron is put into a calorimeter (see sketch attached) that contains 100.0 g of water. The iron sample starts off at 85.0 °C and the temperature of the water starts off at 23.0 °C. When the temperature of the water stops changing it's 27.6 °C. The pressure remains constant at 1 atm.

Calculate the specific heat capacity of iron according to this experiment. Be sure your answer is rounded to the correct number of significant digits

(Question attached)

Answer:

c_{iron}=0.568 J/kg.\°C

c_{iron}=0.6 J/kg.\°C (rounded to 1 decimal place)

Explanation:

A calorimeter is used to measure the heat of chemical or physical reactions. The example given in the question is using the calorimeter to determine the specific heat capacity of iron.

When the system reaches equilibrium the iron and water will be the same temperature, T_{e}. The energy lost from the iron will be equal to the energy gained by the water. It is assumed that the only heat exchange is between the iron and water and no exchange with the surroundings.

Q=mc(T_{e}-T_{initial}) (Eq 1)

-Q_{iron}=Q_{water} (Eq 2)

Water:

m_{water}=100.0 g, c_{water}=4.186 J/kg.\°C, T_{initial,water}=23 \°C, T_{e}=27.6 \°C

Iron:

m_{iron}=59.1 g, c_{iron} = ? J/kg.\°C, T_{initial,iron}=85 \°C, T_{e}=27.6 \°C

Substituting Eq 1 into Eq 2 and details extracted from the question:

-m_{iron}c_{iron}(T_{iron,e}-T_{initial})=m_{water}c_{water}(T_{water,e}-T_{initial})

-59.1*c_{iron}(27.6-85)=100.0*4.186(27.6-23)

c_{iron}=0.568 J/kg.\°C

c_{iron}=0.6 J/kg.\°C

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Moist air initially at 1258C, 4 bar, and 50% relative humidity is contained in a 2.5-m3 closed, rigid tank. The tank contents ar
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Here is the missing part of the question

To Determine the heat transfer, in kJ  if the final temperature in the tank is 110 deg C

Answer:

Explanation:

The image attached below shows the process on T - v diagram

<u>At State 1:</u>

The first step is to find the vapor pressure

P_{v1} = \rho_1 P_g_1

= \phi_1 P_{x  \ at \ 125^0C}

= 0.5 × 232 kPa

= 116 kPa

The initial specific volume of the vapor is:

P_{v_1} v_{v_1} = \dfrac{\overline R}{M_v}T_1

116 \times 10^3 \times v_{v_1} = \dfrac{8314}{18} \times (125 + 273)

116 \times 10^3 \times v_{v_1} = 183831.7778

v_{v_1} = 1.584 \ m^3/kg

<u>At State 1:</u>

The next step is to determine the mass of water vapor pressure.

m_{v1} = \dfrac{V}{v_{v1}}

= \dfrac{2.5}{1.584}

= 1.578 kg

Using the ideal gas equation to estimate the mass of the dry air m_aP_{a1} V = m_a \dfrac{\overline R}{M_a}T_1

(P_1-P_{v1})  V = m_a \dfrac{\overline R}{M_a}T_1

(4-1.16) \times 10^5 \times 2.5 = m_a \dfrac{8314}{28.97}\times ( 125 + 273)

710000= m_a \times 114220.642

m_a = \dfrac{710000}{114220.642}

m_a = 6.216 \ kg

For the specific volume v_{v_1} = 1.584 \ m^3/kg , we get the identical value of saturation temperature

T_{sat} = 100 + (110 -100) \bigg(\dfrac{1.584-1.673}{1.210 - 1.673}\bigg)

T_{sat} =101.92 ^0\ C

Thus, at T_{sat} =101.92 ^0\ C, condensation needs to begin.

However, since the exit temperature tends to be higher than the saturation temperature, then there will be an absence of condensation during the process.

Heat can now be determined by using the formula

Q = ΔU + W

Recall that: For a rigid tank, W = 0

Q = ΔU + 0

Q = ΔU

Q = U₂ - U₁

Also, the mass will remain constant given that there will not be any condensation during the process from state 1 and state 2.

<u>At State 1;</u>

The internal energy is calculated as:

U_1 = (m_a u_a \ _{ at \ 125^0 C})+ ( m_{v1} u_v \ _{ at \ 125^0 C} )

At T_1 = 125° C, we obtain the specific internal energy of air

SO;

U_{a \ at \ 125 ^0C } = 278.93 + ( 286.16 -278.93) (\dfrac{398-390}{400-390}   )

=278.93 + ( 7.23) (\dfrac{8}{10}   )

= 284.714 \ kJ/kg\\

At T_1 = 125° C, we obtain the specific internal energy of  water vapor

U_{v1 \ at \ 125^0C} = u_g = 2534.5 \ kJ/kg

U_1 = (m_a u_a \ at \ _{  125 ^0C }) + ( m_{v1} u_v  \ at \ _{125^0C} )

= 6.216 × 284.714 + 1.578 × 2534.5

= 5768.716 kJ

<u>At State 2:</u>

The internal energy is calculated as:

U_2 = (m_a u_a \ _{ at \ 110^0 C})+ ( m_{v1} u_v \ _{ at \ 110^0 C} )

At temperature 110° C, we obtain the specific internal energy of air

SO;

U_{a \ at \ 110^0C } = 271.69+ ( 278.93-271.69) (\dfrac{383-380}{390-380}   )

271.69+ (7.24) (0.3)

= 273.862 \ kJ/kg\\

At temperature 110° C, we obtain the specific internal energy of  water vapor

U_{v1 \ at \ 110^0C}= 2517.9 \ kJ/kg

U_2 = (m_a u_a \ at \ _{  110 ^0C }) + ( m_{v1} u_v  \ at \ _{110^0C} )

= 6.216 × 273.862 + 1.578 × 2517.9

= 5675.57 kJ

Finally, the heat transfer during the process is

Q = U₂ - U₁

Q = (5675.57 - 5768.716 ) kJ

Q = -93.146 kJ

with the negative sign, this indicates that heat is lost from the system.

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