Answer:
The structure is shown below.
Explanation:
To draw a structure first we need to know its molecular formula, which is C2H6SO for dimethyl sulfoxide. The central atom is sulfur, which is bonded to an oxygen and with two methyl groups (CH3).
Sulfur has 6 electrons in its valence shell, as so oxygen. To complete the octet of oxygen, 2 electrons will be shared by sulfur with it. So, it remains 4 electrons at the central atom. Carbon has 4 electrons in its valence shell, so it needs more 4 to be stable, and is already sharing 3 electrons with the hydrogens, thus, sulfur will share one electron with each one of them.
So, it will remain 2 nonbonding electrons in the central atom. According to the VSPER theory, to minimize formal charges, the structure would be a trigonal pyramid, but, the double bonding with oxygen has a large volume, then the geometry will be trigonal, as shown below.
Answer:
Explanation:
Assumptions
- They would ionize completely, or you must assume that.
- The volumes must be the same as well.
- 0.11M Cu(NO3)2 ===> 0.11MCu2+ + 0.22 NO3-
Note
The concentrations would merely add. All things change if the assumptions I've made are not true.
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*Since my first comment was deleted for supposedly being copied and pasted(which it wasn't) I'm leaving this here. It was NOT copied and pasted!!*
Here we have to get the correct statements among the given, applicable for Diels-Alder reaction.
The true statements in case Diels-Alder reaction are-
1. An excess of Maleic anhydride is used.
2. The I.R. of the products are indistinguishable.
The Diels-Alder reaction is the most is the most important cyclo-addition reaction in organic chemistry. These are addition reactions in which ring systems are formed without eliminating any compounds.
There remains one diene and one dienophile. The reaction is reversible in nature and requires elevated temperature to obtain its transition state. The reaction rate become faster in certain condition like using of polar solvents.
Among the given statements the following statements are true-
1. An excess of maleic anhydride (the most effective di-enophile) is used to process the reaction in forward direction.
2. The products obtain in this reaction are stereoisomers thus are indistinguishable by infrared spectroscopy (IR).
The statements which are not true for the Diels-Alder reaction:
3. The re-crystallization of the products by any polar solvent like methanol is not feasible as it will cause the retro reaction due to stability of the transition state in polar solvent.
4. Cleaning of glassware are compulsory for any reaction it is not specifically true for Diels-Alder reaction.
5. The reaction occurs at elevated temperature thus flame is required.
The correct answer is C, too deep in the Earth to collect. Hope this helps!