When edible oils are idle and stored for a long amount of time, they undergo oxidation due to the exposure to oxygen. This oxidation causes rancidity in oils.
The equation for the reaction is:
C₄H₈O₂ + C₂H₅OH = C₆H₁₂O₂ + H₂O
Now you see that the number of the moles of butanoic acid
and etyl butyrate is equal in
the reaction. That means;
number of moles of C₄H₈O₂ = number of moles of C₆H₁₂O₂
mass of C₄H₈O₂/ Molar mass of C₄H₈O₂ = mass of C₆H₁₂O₂/ molar mass of C₆H₁₂O₂
mass of C₆H₁₂O₂ = molar mass of C₆H₁₂O₂ x mass of C₄H₈O₂/ Molar mass of C₄H₈O₂
Now, assuming <span>100% yield, the mass
of ethyl butyrate produced is: </span>
<span>= 7.45/88.11 x 116.16</span>
<span>=9.82g</span>
<span>Thus, the theoretical yield of ethyl butyrate is 9.82g.</span>
Answer:
Explanation:
M(s) → M (g ) + 20.1 kJ --- ( 1 )
X₂ ( g ) → 2X (g ) + 327.3 kJ ---- ( 2 )
M( s) + 2 X₂(g) → M X₄ (g ) - 98.7 kJ ----- ( 3 )
( 3 ) - 2 x ( 2 ) - ( 1 )
M( s) + 2 X₂(g) - 2 X₂ ( g ) - M(s) → M X₄ (g ) - 98.7 kJ - 2 [ 2X (g ) + 327.3 kJ ] - M (g ) - 20.1 kJ
0 = M X₄ (g ) - 4 X (g ) - M (g ) - 773.4 kJ
4 X (g ) + M (g ) = M X₄ (g ) - 773.4kJ
heat of formation of M X₄ (g ) is - 773.4 kJ
Bond energy of one M - X bond = 773.4 / 4 = 193.4 kJ / mole
Answer:
ΔS° = -268.13 J/K
Explanation:
Let's consider the following balanced equation.
3 NO₂(g) + H₂O(l) → 2 HNO₃(l) + NO(g)
We can calculate the standard entropy change of a reaction (ΔS°) using the following expression:
ΔS° = ∑np.Sp° - ∑nr.Sr°
where,
ni are the moles of reactants and products
Si are the standard molar entropies of reactants and products
ΔS° = [2 mol × S°(HNO₃(l)) + 1 mol × S°(NO(g))] - [3 mol × S°(NO₂(g)) + 1 mol × S°(H₂O(l))]
ΔS° = [2 mol × 155.6 J/K.mol + 1 mol × 210.76 J/K.mol] - [3 mol × 240.06 J/K.mol + 1 mol × 69.91 J/k.mol]
ΔS° = -268.13 J/K
Answer:
Bromine is found in Group 17, Period 4 on the periodic table.
